The asymmetric catalytic synthesis of 1,2-diamines has received considerable interest, due to their presence in biologically active compounds and their applications for the development of synthetic building blocks, chiral ligands and organocatalysts.
A review is presented of magnesium catalysis for the synthesis of important chiral scaffolds. Several important chiral motifs that are present in classic ligands or natural products synthesized by Mg(II) catalytic methods are briefly discussed.
This review aims to provide a thorough overview of recent advancements in the synthesis of chiral vicinal amino alcohols, with a particular focus on strategic developments over the past two decades.
Fluorinated counteranions enable enantioselective synthesis of vicinal amino alcohols.
This review aims to collect advancements in enantioselective palladium-catalyzed cyclization reactions over the past eleven years, and it is organized into thirteen sections depending on the different types of transformations involved.