Engineering hydrophobic–aerophilic interfaces to boost N2 diffusion and reduction through functionalization of fluorine in second coordination spheres

Sakshi Bhardwaj, Sabuj Kanti Das, Ashmita Biswas, Samadhan Kapse, Ranjit Thapa and Ramendra Sundar Dey

Chem. Sci., 2023, 14, 8936
DOI: 10.1039/D3SC03002D

MBene promoted Zn peroxide chemistry in rechargeable near-neutral Zn–air batteries

Yue Hou, Ze Chen, Xinliang Li, Yiqiao Wang, Pei Li, Huilin Cui, Rong Zhang, Shuo Yang, Shaoce Zhang and Chunyi Zhi

Energy Environ. Sci., 2023, 16, 3407
DOI: 10.1039/D3EE01297B

Making chemicals from the air: the new frontier for hybrid electrosyntheses in artificial tree-like devices

Gabriele Centi and Siglinda Perathoner

Green Chem., 2024, 26, 15
DOI: 10.1039/D3GC02135A

Light-driven nitrogen fixation routes for green ammonia production

Laura Collado, Alejandro H. Pizarro, Mariam Barawi, Miguel García-Tecedor, Marta Liras and Víctor A. de la Peña O'Shea

Chem. Soc. Rev., 2024, 53, 11334
DOI: 10.1039/D3CS01075A

Environmental and biomedical applications of 2D transition metal borides (MBenes): recent advancements

Siavash Iravani, Atefeh Zarepour, Arezoo Khosravi and Ali Zarrabi

Nanoscale Adv., 2025, 7, 670
DOI: 10.1039/D4NA00867G

The journey of iron-based electrocatalytic materials for nitrogen reduction reaction: from current status to future prospects

Yi-Han Wang, Ji-Hong Dong, Zhenquan Tan, Xiao-Feng Wang and Xue-Zhi Song

J. Mater. Chem. A, 2023, 11, 11048
DOI: 10.1039/D3TA01548C

Synergistic N/F Dual-Doped MoC/C Catalyst Synthesized via Liquid Phase Plasma for Sustainable Ammonia Production

Chang-Hyeon Park, Ui-Jun Kim, Jae-Hyuk Choi and Seung-Hyo Lee

ACS Appl. Mater. Interfaces, 2024, 16, 63540
DOI: 10.1021/acsami.4c12535

Ternary Heteroatom-Doped Carbon As a High-Performance Metal-Free Catalyst for Electrochemical Ammonia Synthesis

Sakshi Bhardwaj, Sayed Julphukar Alli, Narad Barman, Ranjit Thapa and Ramendra Sundar Dey

ACS Appl. Mater. Interfaces, 2025, 17, 26661
DOI: 10.1021/acsami.5c02039

Self-Assembling of a Mo–Al Composite toward Efficient Catalysts for RWGS Reaction: Overcoming the Trade-off between Ultrasmall Size and High Loading

Shuo Cao, Ying Ma, Wei Chu, Bingsen Zhang, Bo Peng and Yuefeng Liu

ACS Catal., 2025, 15, 15559
DOI: 10.1021/acscatal.5c02942

Advancing sustainable ammonia synthesis with the magnetic La-doped Ti3C2O2 MXenes

Koua Alain Jesus Koua, Jiahe Peng and Neng Li

Progress in Natural Science: Materials International, 2024, 34, 1184
DOI: 10.1016/j.pnsc.2024.09.005

Progress in Single/Multi Atoms and 2D‐Nanomaterials for Electro/Photocatalytic Nitrogen Reduction: Experimental, Computational and Machine Leaning Developments

Aditya Narayan Singh, Rohit Anand, Mohammad Zafari, Miran Ha and Kwang S. Kim

Advanced Energy Materials, 2024, 14
DOI: 10.1002/aenm.202304106

Investigation Optical Properties of ZnTe@Ag Core-Shell Spherical Nanocomposites Within Varies Dielectric Host Matrices

Tsegaye Atnaf and Shewa Getachew

AM, 2024, 13, 80
DOI: 10.11648/j.am.20241304.13

Edge-hosted CoFeB active sites with graphene nanosheets for highly selective nitrogen reduction reaction towards ambient ammonia synthesis

Muhammad Arif, Anuj Kumar, Muhammad Asim Mushtaq, Umair Azhar, Muhammad Sagir, Muhammad Bilal Tahir, Unaiza Talib, Saira Ajmal, Khalid M. Alotaibi and Ghulam Yasin

Chemical Engineering Journal, 2023, 473, 145368
DOI: 10.1016/j.cej.2023.145368

Recent challenges and development of technical and technoeconomic aspects for hydrogen storage, insights at different scales; A state of art review

Ali Saberi Mehr, Andrew D. Phillips, Michael P. Brandon, Mary T. Pryce and James G. Carton

International Journal of Hydrogen Energy, 2024, 70, 786
DOI: 10.1016/j.ijhydene.2024.05.182

Elevating the energy efficiency for the power-to-ammonia conversion: Role of oxygen evolution reaction kinetics

Ashmita Biswas and Ramendra Sundar Dey

The Journal of Chemical Physics, 2023, 158
DOI: 10.1063/5.0153706

Engineering green ammonia photoproduction from nitrogen: Advances, challenges and perspectives

Ying Tang, Yang Song, Juan Jia, Zhipeng Liu, Hui Zeng, Xue Yang and Zebao Rui

Journal of Energy Chemistry, 2026, 112, 111
DOI: 10.1016/j.jechem.2025.07.088

High-entropy MXenes for electrocatalytic nitrogen reduction reaction

Alberto Boretti

Journal of Alloys and Compounds Communications, 2025, 8, 100146
DOI: 10.1016/j.jacomc.2025.100146

New Insight into N,S-Doped Carbon Nanosheets Embedded with Ni/NiO Nanocluster Electrocatalysts Derived from Conjugated Polymers for the Oxidation of 2-Propanol to Acetone

Pratiksha D. Tanwade, Arindam Adhikari and Bhaskar R. Sathe

J. Phys. Chem. C, 2024, 128, 4152
DOI: 10.1021/acs.jpcc.3c07977

Role of Lewis acidity and optimum contribution of cobalt and iron on the adsorption and electrochemical reduction of N2 to NH3

Vineet Mishra, Shanmugam Ramasamy, Deep Lata Singh, Merlin P and Ranga Rao Gangavarapu

Catalysis Today, 2025, 445, 115054
DOI: 10.1016/j.cattod.2024.115054

Strategic ligand-induced electronic structure modulation for enhanced nitrogen reduction reaction selectivity in transition metal phthalocyanines

Jae Hun Seol, Seong Chan Cho, Chi Ho Lee and Sang Uck Lee

Chemical Engineering Journal, 2025, 511, 162133
DOI: 10.1016/j.cej.2025.162133

Electrocatalytic nitrogen reduction to ammonia at low overpotentials based on tungsten carbide doped by non-precious metal single cobalt atoms

Ya Gao, Meng-Jiao Zhu, Xian-He Liu, Guo-Liang Dai, Yi-Wen Zhou, Ze-Da Meng, Li Luo, Tian Gan, Feng Chen, Yu-Yang Zhou, Wen-Wen Deng and Shou-Qing Liu

Chemical Engineering Journal, 2024, 493, 152659
DOI: 10.1016/j.cej.2024.152659

Open Frameworks Materials for Nitrogen Electrofixation to Ammonia, Progress, Challenges, and Future Perspectives

Shihai Cao, Jingyu Lu, Yuntong Sun, Yinghao Li, Zhendong Hao and Jong‐Min Lee

Small, 2025, 21
DOI: 10.1002/smll.202502708

Recent progress in Pd based electrocatalysts for electrochemical nitrogen reduction to ammonia

Shehman Assad, Tayyeba Tariq, Muhammad Zaeem Idrees, Abdul Mannan Butt, Khush Bakhat and Umair Shamraiz

Journal of Electroanalytical Chemistry, 2023, 931, 117174
DOI: 10.1016/j.jelechem.2023.117174

p-Block Metal Oxide as an Efficient Electrocatalyst for Boosting Ambient Ammonia Synthesis

Sakshi Bhardwaj, Reshmi T. Parayil, Santosh K. Gupta and Ramendra Sundar Dey

Energy Fuels, 2024, 38, 11321
DOI: 10.1021/acs.energyfuels.4c01741

Machine-Learned Force Field for Molecular Dynamics Simulations of Nonequilibrium Ammonia Synthesis on Iron Catalysts

Aditya Dilip Lele, Zhiyu Shi, Shrey Khetan, Emily A. Carter, John Mark P. Martirez and Yiguang Ju

J. Phys. Chem. C, 2025, 129, 4937
DOI: 10.1021/acs.jpcc.4c07596

Cutting-edge advances in pressurized electrocatalytic reactors

Yang Li, Guining Shao, Xinyu Zheng, Yansong Jia, Yanghong Xia, Yuhai Dou, Ming Huang, Chaohua Gu, Jianfeng Shi, Jinyang Zheng and Shixue Dou

eScience, 2025, 5, 100369
DOI: 10.1016/j.esci.2024.100369

Controlling activation, selectivity, and transport in photocatalytic N2 reduction to ammonia

Suqin Han, Kerun Zhang, Wenjing Tian, Jiewen Hou, Hui-Zi Huang, Lan Bao, Mingming Gao, Hongyu Mou, Xing Gao, Liwei Chen, Yuchen Hao and Bo Wang

Coordination Chemistry Reviews, 2026, 560, 217884
DOI: 10.1016/j.ccr.2026.217884

Novel insights into in-situ and ex-situ production of geological ammonia from rocks

Muhammad Imran Rashid

Next Research, 2026, 3, 101177
DOI: 10.1016/j.nexres.2025.101177

2D-Transition Metal Borides (MBenes): a comprehensive review of the materials, chemistry, advances, and novel applications

Mohammad Ramezanzadeh, Reza Ghamarpoor, Ali Dashan, Akram Fallah, Soolmaz Soleimani and Bahram Ramezanzadeh

Adv Compos Hybrid Mater, 2025, 8
DOI: 10.1007/s42114-025-01311-3

The transition metal doped B cluster (TM4B18) as catalysis for nitrogen fixation

Xingzi Fang, Xiaowei Yang and Haifeng Wang

Molecular Catalysis, 2023, 539, 113031
DOI: 10.1016/j.mcat.2023.113031

Lewis Acid Mediated Alteration of Electron Density on a Copper Site via pπ-dπ Mixing Enhances the Electrochemical Nitrogen Reduction Reaction

Surajit Samui and Ramendra Sundar Dey

J. Phys. Chem. Lett., 2024, 15, 2152
DOI: 10.1021/acs.jpclett.4c00233

Review and Perspectives of Electrochemical Energy Conversion and Storage in Metal Diborides and XBenes

Anupma Thakur, Anshul Rasyotra and Kabeer Jasuja

Energy Fuels, 2023, 37, 18310
DOI: 10.1021/acs.energyfuels.3c02785

Recent trend in rare earth electrocatalysts for ambient ammonia synthesis: Challenges and perspectives

Muhammad Asim Mushtaq, Waseem Raza, Munir Ahmad, Anuj Kumar, Andleeb Mehmood, Muhammad Arif, Ghulam Yasin, Mohammad Tabish, Saira Ajmal, Muhammad Ahmad, Muhammad Sufyan Javed and Dongpeng Yan

Journal of Rare Earths, 2026, 44, 519
DOI: 10.1016/j.jre.2025.11.020

Efficient Nitric Oxide Reduction to Ammonia via Vacancy‐Driven Specific Capture and Activation on a Mo2N‐Based Catalyst

Na Li, Zhenkun Xie, Yanyan Yang, Song Yang, Huilin Tao, Yuxuan Lu, Zeyu Liu, Jie Zheng, Yongfan Zhang and Zhongliang Yu

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202501455

Two-dimensional MBenes for next-generation energy storage and electrocatalysis

Chhavi Jaswal, Manjot Kaur and Akshay Kumar

Applied Energy, 2026, 414, 127799
DOI: 10.1016/j.apenergy.2026.127799

Computational investigation of electrocatalytic ammonia synthesis on Mo-doped C24N24 fullerene

Muhammad Junaid, Sajid Karam, Muhammad Iqbal and Mehran Anjum

J Mol Model, 2025, 31
DOI: 10.1007/s00894-025-06425-5

A green ammonia utilization pathway: Integrated ammonia-solid oxide fuel cell systems for efficient power generation

Xusheng Wang, Mingchen Gao, Alexander R.P. Harrison, Muhammad Irfan, Xi Lin, Boyang Mao, Binjian Nie, Zhigang Hu and Jianxin Zou

EnergyChem, 2025, 7, 100167
DOI: 10.1016/j.enchem.2025.100167

Recent advances and intensifications in Haber-Bosch ammonia synthesis process

Navid Erfani, Luqmanulhakim Baharudin and Matthew Watson

Chemical Engineering and Processing - Process Intensification, 2024, 204, 109962
DOI: 10.1016/j.cep.2024.109962

Heteronuclear Trimetallic MFe2 and M2Fe (M=V, Nb, and Ta) Clusters for Dinitrogen Activation

Ya Ya Wang, Xun‐Lei Ding, Zhi‐Wen Ji, Xiao‐Meng Huang and Wei Li

ChemPhysChem, 2023, 24
DOI: 10.1002/cphc.202200952

Molybdenum carbide nanosheets with iron doping as electrocatalysts for highly efficient ammonia electrosynthesis

Muhammad Adnan Younis, Ahmed I. Osman, Amjad Ali, Fazal Haq, Tariq Aziz, Mehwish Kiran, Iffat Ayesha Khan, Rizwan Wahab and Saira Manzoor

Journal of Electroanalytical Chemistry, 2024, 975, 118749
DOI: 10.1016/j.jelechem.2024.118749

Ultra-Low Loading of Gold on Nickel Foam for Nitrogen Electrochemistry

Giuseppe Tranchida, Rachela G. Milazzo, Marco Leonardi, Silvia Scalese, Roberta A. Farina, Salvatore Lombardo and Stefania M. S. Privitera

Nanomaterials, 2023, 13, 2850
DOI: 10.3390/nano13212850

Electrocatalytic ammonia synthesis on bimetallic AuPd porous structures

Yue Pang, Guorui Tang, Shulin Zhao, Yijie Yang and Cheng-Peng Li

Inorganic Chemistry Communications, 2024, 169, 113026
DOI: 10.1016/j.inoche.2024.113026

Vacancy Rich TiB2 Nanosheets Promote Electrochemical Ammonia Synthesis

Anshul Rasyotra, Anupma Thakur, Bhagyashri Gaykwad, Raviraj Mandalia, Raghavan Ranganathan and Kabeer Jasuja

ACS Appl. Mater. Interfaces, 2024, 16, 24473
DOI: 10.1021/acsami.4c00253

High‐Efficiency Electrochemical Nitrogen Fixation by Noble‐Metal‐Free Metallic Glasses

Xue Chen, Xin‐Jie Peng, Dong‐Dong Xiao, Yi‐Tao Sun, Kai‐Ling Zhou, Xiao‐Yong Yang, Yong‐Zheng Zhang, Wei‐Hua Wang, Zhen Lu and Hai‐Yang Bai

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202503400

Interlinking electronic band properties in catalysts with electrochemical nitrogen reduction performance: a direct influence

Ashmita Biswas, Surajit Samui and Ramendra Sundar Dey

Electron. Struct., 2024, 6, 023001
DOI: 10.1088/2516-1075/ad3123

Recent advances in the sustainable potential of 2D MBenes for diverse applications: A comprehensive review

Ubaid Ur Rehman, Kashaf Ul Sahar and Chun-Ming Wang

Sustainable Materials and Technologies, 2025, 45, e01427
DOI: 10.1016/j.susmat.2025.e01427

MXene-based catalysts for electrochemical nitrate and nitrogen reduction: A review toward sustainable nitrogenous fuels

Ubaid Ullah Jan, Kiruthika Mariappan, Subramanian Sakthinathan, Te-Wei Chiu, Yu-Han Tsai, Muhammad Sheraz Ahmad, Arshid Numan, Chao-Lin Liu and Ching-Lung Chen

Sustainable Materials and Technologies, 2026, 47, e01892
DOI: 10.1016/j.susmat.2026.e01892

A High-Throughput Screening toward Efficient Nitrogen Fixation: Transition Metal Single-Atom Catalysts Anchored on an Emerging π–π Conjugated Graphitic Carbon Nitride (g-C10N3) Substrate with Dirac Dispersion

Qiang Zhang, Xian Wang, Fuchun Zhang, Chunyao Fang, Di Liu and Qingjun Zhou

ACS Appl. Mater. Interfaces, 2023, 15, 11812
DOI: 10.1021/acsami.2c22519

Green Ammonia Unleashed: Cutting-Edge Electrochemical Synthesis, Catalyst Innovations, and SOFC Integration for a Sustainable Energy Future─A Review and Perspectives

Khadija Tnifasse, Kenza Bouchaala, Mustapha Faqir and El Hachmi Essadiqi

Energy Fuels, 2025, 39, 1793
DOI: 10.1021/acs.energyfuels.4c04978

Surface Oxidation of Transition Metal Nitrides

Ji Liu, Jean-Pierre Glauber, Julian Lorenz, Detlef Rogalla, Corinna Harms, Anjana Devi and Michael Nolan

J. Phys. Chem. C, 2025, 129, 11173
DOI: 10.1021/acs.jpcc.5c02303

Ambient Electrochemical Ammonia Synthesis From Various Nitrogen Sources

Aya Assafiri, Quentin Meyer, Chen Jia, David Brynn Hibbert and Chuan Zhao

Small, 2026, 22
DOI: 10.1002/smll.202511987

Selective Dinitrogen Electroreduction to Ammonia on Zn2V2O7 Pyrochlore

Naina Goyal, Shweta Choudhary, Benedict Witulski, Shuai Yan, Bhupendra Singh, Nikolay Kornienko, Swastika Banerjee and Sanjay Mathur

ACS Catal., 2026, 16, 2522
DOI: 10.1021/acscatal.5c07714

Mo-Nitrogen nexus: Nanotechnology enhanced Mo-based nitrogen fixation towards environmental sustainability

Samina Irshad, Yu Xie, Yaping Lyu, Ziqi Zhang, Xingxin Liu, Haojie Wei, Beza Tuga, Christy L. Haynes, Yaqi Jiang, Yi Sun, Jason C. White, Yukui Rui and Peng Zhang

Chemical Engineering Journal, 2025, 523, 168358
DOI: 10.1016/j.cej.2025.168358

Revisiting the Electrochemical Nitrogen Reduction on Molybdenum and Iron Carbides: Promising Catalysts or False Positives?

Boaz Izelaar, Davide Ripepi, Simone Asperti, A. Iulian Dugulan, Ruud W.A. Hendrikx, Amarante J. Böttger, Fokko M. Mulder and Ruud Kortlever

ACS Catal., 2023, 13, 1649
DOI: 10.1021/acscatal.2c04491

Engineering Catalytically Active Sites by Sculpting Artificial Edges on MoS2 Basal Plane for Dinitrogen Reduction at a Low Overpotential

Renu Rani, Ashmita Biswas, Raihan Ahammed, Taniya Purkait, Anirban Kundu, Subhajit Sarkar, Mamta Raturi, Abir De Sarkar, Ramendra Sundar Dey and Kiran Shankar Hazra

Small, 2023, 19
DOI: 10.1002/smll.202206357