Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts and Stefaan M. A. De Wildeman

Green Chem., 2020, 22, 2443
DOI: 10.1039/C9GC02088H

Enantioselective Oxidative Multi-Functionalization of Terminal Alkynes with Nitrones and Alcohols for Expeditious Assembly of Chiral α-Alkoxy-β-amino-ketones

Su Zhou, Yinwu Li, Xiangrong Liu, Wenhao Hu, Zhuofeng Ke and Xinfang Xu

J. Am. Chem. Soc., 2021, 143, 14703
DOI: 10.1021/jacs.1c06178

Catalysts Based on the C−H⋅⋅⋅M Weak Interaction: Synthesis, Characterization and Catalytic Application of Bis(pyrazolyl)borate Cu(I) Complexes in Carbene Insertion into Heteroatom Hydrogen Bonds

Qianyi Zhao, Qiu‐Yue Yao, Ting Dou, Ting Xu, Jie Zhang and Xuenian Chen

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202200552

Visible-Light-Promoted Aerobic Oxyphosphorylation of α-Diazoesters with H-Phosphine Oxides

Hongyan Zhou, Ganggang Wang, Cunhui Wang and Jingya Yang

Org. Lett., 2022, 24, 1530
DOI: 10.1021/acs.orglett.2c00198

Palladium-Catalyzed Allylic Alkylation via Photocatalytic Nucleophile Generation

Yang Shen, Zhen-Yao Dai, Cheng Zhang and Pu-Sheng Wang

ACS Catal., 2021, 11, 6757
DOI: 10.1021/acscatal.1c01500

Rhodium/Gold Dual Catalysis in Carbene sp2 C−H Functionalization/Conia‐ene Cascade for the Stereoselective Synthesis of Diverse Spirocarbocycles

Arianne C. Hunter, Kiran Chinthapally, Anae I. Bain, Joseph C. Stevens and Indrajeet Sharma

Adv Synth Catal, 2019, 361, 2951
DOI: 10.1002/adsc.201900079

A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth–Rhodium Paddlewheel Catalysts

Santanu Singha, Michael Buchsteiner, Giovanni Bistoni, Richard Goddard and Alois Fürstner

J. Am. Chem. Soc., 2021, 143, 5666
DOI: 10.1021/jacs.1c01972

Catalyst Free Chemoselective Carbene Insertion Into COO─H Bond Over ─OH of Salicylic Acid

Gruhapriya Jelakam, Swaraj Dey, Vikiho Wotsa and Chinnappan Sivasankar

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202405088

Enantioselective Synthesis of Unnatural Carbamate-Protected α-Alkyl Amino Esters via N–H Bond Insertion Reactions

You Li, Yu-Xuan Su, Yu-Tao Zhao, Lu Liu, Mao-Lin Li and Shou-Fei Zhu

ACS Catal., 2022, 12, 13143
DOI: 10.1021/acscatal.2c03937

Silver‐Catalyzed Asymmetric Insertion into Phenolic O−H Bonds using Aryl Diazoacetates and Theoretical Mechanistic Studies

Shingo Harada, Koki Tanikawa, Haruka Homma, Chigaya Sakai, Tsubasa Ito and Tetsuhiro Nemoto

Chemistry A European J, 2019, 25, 12058
DOI: 10.1002/chem.201902126

Highly Enantioselective Brønsted Acid Catalyzed Heyns Rearrangement

Jin Cao, Yu‐Xuan Su, Xin‐Yu Zhang and Shou‐Fei Zhu

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202212976

Catalyst-Dependent Asymmetric Dearomative and Desymmetrizative Higher-Order [8 + 2] Cycloaddition of Indolizines with Maleimides toward the Atroposelective Synthesis of Cyclazines

Thiago S. Silva, José T. M. Correia, Bruno A. Piscelli, Rodrigo A. Cormanich, Benjamin List and Fernando Coelho

ACS Catal., 2025, 15, 13558
DOI: 10.1021/acscatal.5c03020

Overview of Transition Metal Catalyzed Multicomponent Reactions Based on Trapping of Allylic Electrophiles

Kriti Gupta, Mahesh Singh Harariya, Arushi Tyagi and Garima Jindal

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301215

Chemo‐ and Enantioselective Insertion of Furyl Carbene into the N−H Bond of 2‐Pyridones

Kai Wang, Ziye Liu, Guangyang Xu, Ying Shao, Shengbiao Tang, Ping Chen, Xinhao Zhang and Jiangtao Sun

Angewandte Chemie, 2021, 133, 17079
DOI: 10.1002/ange.202104708

Catalytic N‐H Insertion Reactions with α‐Diazoacetates: An Efficient Method for Enantioselective Amino Acid Synthesis

Yu‐Xuan Su, Ming‐Yao Huang and Shou‐Fei Zhu

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300539

Chiral Dirhodium Tetraphosphate-Catalyzed Enantioselective Si–H Bond Insertion of α-Aryldiazoacetates

Liang-Liang Yang, Jin Cao, Tian-Yuan Zhao, Shou-Fei Zhu and Qi-Lin Zhou

J. Org. Chem., 2021, 86, 9692
DOI: 10.1021/acs.joc.1c00967

Rhodium-Catalyzed Intramolecular Cyclization to Synthesize 2-Aminobenzofurans via Carbene Metathesis Reactions

Xue Li, Heyun Sheng and Qiuling Song

Org. Lett., 2023, 25, 2113
DOI: 10.1021/acs.orglett.3c00539

Asymmetric Catalytic [2,3] Stevens and Sommelet–Hauser Rearrangements of α‐Diazo Pyrazoleamides with Sulfides

Xiaobin Lin, Wei Yang, Wenkun Yang, Xiaohua Liu and Xiaoming Feng

Angewandte Chemie, 2019, 131, 13626
DOI: 10.1002/ange.201907164

Catalytic Asymmetric Access to Noncanonical Chiral α-Amino Acids from Cyclic Iminoglyoxylates and Enamides

Yue Zhang, Jun-Kuan Li, Fa-Guang Zhang and Jun-An Ma

J. Org. Chem., 2020, 85, 5580
DOI: 10.1021/acs.joc.0c00436

Three Ways Isolable Carbenes Can Modulate Emission of NH-Containing Fluorophores

Jerod M. Kieser, Zacharias J. Kinney, Joshua R. Gaffen, Sloane Evariste, Alexandra M. Harrison, Arnold L. Rheingold and John D. Protasiewicz

J. Am. Chem. Soc., 2019, 141, 12055
DOI: 10.1021/jacs.9b04864

The Power of Iron Catalysis in Diazo Chemistry

Virginie Carreras, Nour Tanbouza and Thierry Ollevier

Synthesis, 2021, 53, 79
DOI: 10.1055/s-0040-1707272

Catalytic (4+2) Annulation via Regio‐ and Enantioselective Interception of in‐situ Generated Alkylgold Intermediate

Ming Bao, Yi Zhou, Haoxuan Yuan, Guizhi Dong, Chao Li, Xiongda Xie, Kewei Chen, Kemiao Hong, Zhi‐Xiang Yu and Xinfang Xu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202401557

Indanone derivatives: Emerging frontiers in cancer therapy

Dipanjan Karati, Dhrubojyoti Sen, Beduin Mahanti, Souvik Roy and Swarupananda Mukherjee

Synthetic Communications, 2025, 55, 1501
DOI: 10.1080/00397911.2025.2530181

A Spiro Phosphamide Catalyzed Enantioselective Proton Transfer of Ylides in a Free Carbene Insertion into N−H Bonds

Jia‐Bin Pan, Xuan‐Ge Zhang, Yi‐Fan Shi, Ai‐Cui Han, Yu‐Jia Chen, Jing Ouyang, Mao‐Lin Li and Qi‐Lin Zhou

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202300691

A Bifunctional Copper Catalyst Enables Ester Reduction with H2: Expanding the Reactivity Space of Nucleophilic Copper Hydrides

Birte M. Zimmermann, Trung Tran Ngoc, Dimitrios-Ioannis Tzaras, Trinadh Kaicharla and Johannes F. Teichert

J. Am. Chem. Soc., 2021, 143, 16865
DOI: 10.1021/jacs.1c09626

Multifunctional Biocatalysts for Organic Synthesis

Thomas W. Thorpe, James R. Marshall and Nicholas J. Turner

J. Am. Chem. Soc., 2024, 146, 7876
DOI: 10.1021/jacs.3c09542

Synthesis and Resolution of an Axially Chiral Spirocyclic Quaternary Ammonium Ion‐Based Phase‐Transfer Catalyst

Shen Li, Hui Zhou and Benjamin List

Asian J Org Chem, 2023, 12
DOI: 10.1002/ajoc.202300241

Recent Progress in Asymmetric Relay Catalysis of Metal Complex with Chiral Phosphoric Acid

Pu-Sheng Wang, Dian-Feng Chen and Liu-Zhu Gong

Top Curr Chem (Z), 2020, 378
DOI: 10.1007/s41061-019-0263-2

Chiral Spiro Phosphoric Acid-Catalyzed Friedel–Crafts Conjugate Addition/Enantioselective Protonation Reactions

Yi-Pan Li, Zi-Qi Li, Biying Zhou, Mao-Lin Li, Xiao-Song Xue, Shou-Fei Zhu and Qi-Lin Zhou

ACS Catal., 2019, 9, 6522
DOI: 10.1021/acscatal.9b01502

Asymmetric Carbene Insertion into Se−S Bonds by Synergistic Rh(II)/Guanidine Catalysis Involving Chalcogen‐Bond Assistance

Xin He, Yihua Fu, Ruiying Xi, Cefei Zhang, Kexin Lan, Zhishan Su, Fei Wang, Xiaoming Feng and Xiaohua Liu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202417636

Catalytic reactions for enantioselective transfers of donor-substituted carbenes

Ming-Yao Huang and Shou-Fei Zhu

Chem Catalysis, 2022, 2, 3112
DOI: 10.1016/j.checat.2022.10.016

Cu-Catalyzed Enantioselective Carbene Insertion into Ge–H and Si–H Bonds Enabled by SPSiBox with a Tunable Chiral Pocket

Shi-Hao Chen, Shengye Zhang, Zi-Yang Chen, Yichen Wu and Peng Wang

J. Am. Chem. Soc., 2025, 147, 15666
DOI: 10.1021/jacs.5c02996

Well‐Defined, Versatile and Recyclable Half‐Sandwich Nickelacarborane Catalyst for Selective Carbene‐Transfer Reactions

Linghua Wang, Saima Perveen, Yizhao Ouyang, Shuai Zhang, Jiao Jiao, Gang He, Yong Nie and Pengfei Li

Chemistry A European J, 2021, 27, 5754
DOI: 10.1002/chem.202005014

Progress on Pyridotriazole Chemistry: Synthesis and Transformations

Ruwei Shen, Kaixin Yin, Mengyuan Yu and Xiaojie Li

Asian J Org Chem, 2023, 12
DOI: 10.1002/ajoc.202200631

Chiral Isourea-Catalyzed Enantioselective Carbene Insertion into an N–H Bond through a Double Proton-Transfer Process

Xuan-Ge Zhang, Jun-Jia Chen, Meng-Chun Ye, Xiao-Hua Liu and Qi-Lin Zhou

J. Am. Chem. Soc., 2026, 148, 13513
DOI: 10.1021/jacs.6c01890

Catalytic Asymmetric P–H Insertion Reactions

Xiu Gu, Xiaoyu Mo, Wen-Ju Bai, Peng Xie, Wenhao Hu and Jun Jiang

J. Am. Chem. Soc., 2023, 145, 20031
DOI: 10.1021/jacs.3c06906

Construction of α-Acyloxy Ketones via Photoredox-Catalyzed O–H Insertion of Sulfoxonium Ylides with Carboxylic Acids

Qing Sun, Yuzhu Peng, Yujing Wang and Xiaoguang Bao

Org. Lett., 2023, 25, 6613
DOI: 10.1021/acs.orglett.3c02221

Styrene-Based Axial Chiral Catalyst-Catalyzed Asymmetric Synthesis of Spirobarbiturates through Chiral Proton Shuttle

Xiao-Kun Shi, Shen-Yuan Zhang, Tian-Dong Guan, Fu-Xin Tan, Xin-Yu Chen, Yu-Ting Li, Peng-Fei Lian, Tong-Mei Ding and Shu-Yu Zhang

ACS Catal., 2026, 16, 1533
DOI: 10.1021/acscatal.5c07532

Paddlewheel dirhodium(II) complexes with N-heterocyclic carbene or phosphine ligand: New reactivity and selectivity

Biqiong Hong, Lei Shi, Lin Li, Shuming Zhan and Zhenhua Gu

Green Synthesis and Catalysis, 2022, 3, 137
DOI: 10.1016/j.gresc.2022.03.001

Catalytic Hydrogen Transfer Reactions

Shou‐Fei Zhu

Chin. J. Chem., 2021, 39, 3211
DOI: 10.1002/cjoc.202100449

Enantioselective synthesis of fluorinated aromatic amino acids catalyzed by SPINOL-derived chiral quaternary ammonium salts†

Meng-Yu Rong, Jing Nie, Shen Li and Jun-An Ma

Molecular Catalysis, 2024, 552, 113679
DOI: 10.1016/j.mcat.2023.113679

Photoinduced Diverse Reactivity of Diazo Compounds with Nitrosoarenes

Sourav Roy, Gourav Kumar and Indranil Chatterjee

Org. Lett., 2021, 23, 6709
DOI: 10.1021/acs.orglett.1c02279

Glycosylidene-carbene-mediated homologation of boronic esters for the synthesis of boro-ketosides

Qibin Zhu, Xinyu Tian and Gang He

Chem Catalysis, 2024, 4, 100946
DOI: 10.1016/j.checat.2024.100946

Asymmetric Enamide–Imine Tautomerism in the Kinetic Resolution of Tertiary Alcohols

Mengyao Tang, Huanchao Gu, Shunlong He, Subramani Rajkumar and Xiaoyu Yang

Angew Chem Int Ed, 2021, 60, 21334
DOI: 10.1002/anie.202106151

Harnessing thia-Rh-carbenes for the enantioselective synthesis of chiral α,α-diheteroatomic carboxylic acids

Yajie Xing, Yuqi Fang, Yicheng Zhao, Jiean Chen and Yong Huang

Nat Catal, 2026, 9, 173
DOI: 10.1038/s41929-026-01481-3

Dinitrogen extrusion from diazene in organic synthesis

Chunngai Hui, Shiping Wang and Chunfa Xu

Chinese Chemical Letters, 2022, 33, 3695
DOI: 10.1016/j.cclet.2022.03.073

Photoredox Catalysis of Aromatic β‐Ketoesters for in Situ Production of Transient and Persistent Radicals for Organic Transformation

Xiu‐Long Yang, Jia‐Dong Guo, Hongyan Xiao, Ke Feng, Bin Chen, Chen‐Ho Tung and Li‐Zhu Wu

Angew Chem Int Ed, 2020, 59, 5365
DOI: 10.1002/anie.201916423

Enantioselective Silicon-Directed Nazarov Cyclization

Jin Cao, Meng-Yang Hu, Si-Yuan Liu, Xin-Yu Zhang, Shou-Fei Zhu and Qi-Lin Zhou

J. Am. Chem. Soc., 2021, 143, 6962
DOI: 10.1021/jacs.1c01194

Blue‐Light‐Induced Pd‐Catalyzed Quinolinamide‐Directed Regioselective C‐8 Benzylation of 1‐Naphthylamines Using Flow‐Generated Aryldiazomethanes in Batch and Continuous‐Flow

Wei Zhang, Yanxin Xie, Zaikun Xue, Changqing Miao, Jiao Guo and Baoli Zhao

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500849

Axial Ligand Enables Synthesis of Allenylsilane through Dirhodium(II) Catalysis

Wendeng Li, Rui Wu, Hao Ruan, Bo Xiao, Xiang Gao, Huanfeng Jiang, Kai Chen, Tian‐Yu Sun and Shifa Zhu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202409332

Rhodium‐Catalyzed O−H Bond Insertion Reaction between H‐Phosphoryl Compounds and 2‐Pyridyl Carbenes Generated from Pyridotriazoles

Chao Dong, Can Zhang, Xin Wang and Ruwei Shen

Asian J Org Chem, 2021, 10, 1514
DOI: 10.1002/ajoc.202100195

Palladium‐Catalyzed Enantioselective Thiocarbonylation of Styrenes

Xihong Wang, Bing Wang, Xuemei Yin, Wangzhi Yu, Yang Liao, Jialin Ye, Min Wang, Lianrui Hu and Jian Liao

Angew Chem Int Ed, 2019, 58, 12264
DOI: 10.1002/anie.201905905

Cu/chiral phosphoric acid-catalyzed radical-initiated asymmetric aminosilylation of alkene with hydrosilane

Yang Zeng, Xiao-Dong Liu, Xian-Qi Guo, Qiang-Shuai Gu, Zhong-Liang Li, Xiao-Yong Chang and Xin-Yuan Liu

Sci. China Chem., 2019, 62, 1529
DOI: 10.1007/s11426-019-9528-2

Trapping of Zwitterionic Intermediates by Isatins and Imines: Synthesis of Benzoxazines Bearing a C4-Quaternary Stereocenter

Shikun Jia, Xi Yang, Guizhi Dong, Chaoqun Ao, Xianxing Jiang and Wenhao Hu

Org. Lett., 2019, 21, 4014
DOI: 10.1021/acs.orglett.9b01207

Asymmetric Enamide–Imine Tautomerism in the Kinetic Resolution of Tertiary Alcohols

Mengyao Tang, Huanchao Gu, Shunlong He, Subramani Rajkumar and Xiaoyu Yang

Angewandte Chemie, 2021, 133, 21504
DOI: 10.1002/ange.202106151

Rhodium-Catalyzed C═N Bond Formation through a Rebound Hydrolysis Mechanism and Application in β-Lactam Synthesis

Long Chen, Linxing Zhang, Ying Shao, Guangyang Xu, Xinhao Zhang, Shengbiao Tang and Jiangtao Sun

Org. Lett., 2019, 21, 4124
DOI: 10.1021/acs.orglett.9b01312

Disulfonimide catalyzed asymmetric intramolecular hydroamination of alkenyl thioureas: Concentration effect in the hydroamination

Ryukichi Takagi, Duyen Thi Duong and Toshiya Ichiki

Tetrahedron, 2021, 94, 132332
DOI: 10.1016/j.tet.2021.132332

Enantioselective Photochemical Carbene Insertion into C–C and C–H Bonds of 1,3-Diketones by a Guanidine-Amide Organocatalyst

Shiyang Li, Cefei Zhang, Guihua Pan, Liangkun Yang, Zhishan Su, Xiaoming Feng and Xiaohua Liu

ACS Catal., 2023, 13, 4656
DOI: 10.1021/acscatal.3c00192

Brønsted Acid Catalyzed Enantioselective Assembly of Spirochroman-3,3-oxindoles

Alavala Gopi Krishna Reddy, Pedireddi Niharika, Su Zhou, Shi-Kun Jia, Taoda Shi, Xinfang Xu, Yu Qian and Wenhao Hu

Org. Lett., 2020, 22, 2925
DOI: 10.1021/acs.orglett.0c00587

Site-Selective Functionalization of 7-Azaindoles via Carbene Transfer and Isolation of N-Aromatic Zwitterions

Junheng Liu, Guangyang Xu, Shengbiao Tang, Qun Chen and Jiangtao Sun

Org. Lett., 2020, 22, 9376
DOI: 10.1021/acs.orglett.0c03653

Effective Coordination Promoted Carbene N─H Bond Insertion on Heterogeneous Cu Catalyst

Ruixue Zhang, Mingze Sun, Luan Lu, Shu‐Li You, Zhiqiang Niu and Jie Zhao

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202517764

Asymmetric Counter-Anion-Directed Aminomethylation: Synthesis of Chiral β-Amino Acids via Trapping of an Enol Intermediate

Zhenghui Kang, Yongheng Wang, Dan Zhang, Ruibo Wu, Xinfang Xu and Wenhao Hu

J. Am. Chem. Soc., 2019, 141, 1473
DOI: 10.1021/jacs.8b12832

Chiral Spiro Phosphoramide-Catalyzed Sulfa-Michael Addition/Enantioselective Protonation of Exocyclic Enones

Yi-Pan Li, Shou-Fei Zhu and Qi-Lin Zhou

Org. Lett., 2019, 21, 9391
DOI: 10.1021/acs.orglett.9b03615

Rhodium(I)/Chiral Diene-Catalyzed Asymmetric Carbene Transformations

Weici Xu and Ming-Hua Xu

Acc. Chem. Res., 2026, 59, 179
DOI: 10.1021/acs.accounts.5c00726

Asymmetric Carbene Insertion into Se−S Bonds by Synergistic Rh(II)/Guanidine Catalysis Involving Chalcogen‐Bond Assistance

Xin He, Yihua Fu, Ruiying Xi, Cefei Zhang, Kexin Lan, Zhishan Su, Fei Wang, Xiaoming Feng and Xiaohua Liu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202417636

Effective Coordination Promoted Carbene N─H Bond Insertion on Heterogeneous Cu Catalyst

Ruixue Zhang, Mingze Sun, Luan Lu, Shu‐Li You, Zhiqiang Niu and Jie Zhao

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202517764

Asymmetric Catalytic [2,3] Stevens and Sommelet–Hauser Rearrangements of α‐Diazo Pyrazoleamides with Sulfides

Xiaobin Lin, Wei Yang, Wenkun Yang, Xiaohua Liu and Xiaoming Feng

Angew Chem Int Ed, 2019, 58, 13492
DOI: 10.1002/anie.201907164

Enantioselective N–H Insertion of Sulfonamides: Access to Chiral α-Aminoesters

Shaoran An, Ruixi Zheng, Ying Shao, Shengbiao Tang, Zhenya Dai and Jiangtao Sun

Org. Lett., 2025, 27, 10898
DOI: 10.1021/acs.orglett.5c03534

Theoretical study of the substituent effect on the O–H insertion reaction of copper carbenoids

Rocío Durán and Barbara Herrera

Theor Chem Acc, 2022, 141
DOI: 10.1007/s00214-022-02876-8

Sulfur-Mediated Reactions through Sulfonium Salts and Ylides

Pingfan Li

Synlett, 2021, 32, 1275
DOI: 10.1055/a-1409-0906

Synergistic catalytic synthesis of chiral γ-butenolides by trapping carboxylic oxonium ylides with enones and isatins

Xinpeng Sang, Wentao Xu, Yuqiao Zhou, Min Chen, Lili Lin, Minghui Ji, Fei Wang, Shunxi Dong and Xiaoming Feng

Sci. China Chem., 2025, 68, 5007
DOI: 10.1007/s11426-025-2665-x

Catalytic (4+2) Annulation via Regio‐ and Enantioselective Interception of in‐situ Generated Alkylgold Intermediate

Ming Bao, Yi Zhou, Haoxuan Yuan, Guizhi Dong, Chao Li, Xiongda Xie, Kewei Chen, Kemiao Hong, Zhi‐Xiang Yu and Xinfang Xu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202401557

Stereodivergent Four-Component Reactions via Rh-Carbynoids

Jian Luo, Yinwu Li, Haiqing Wang, Gengxin Liu, Zhenghui Kang, Yu Qian, Zhuofeng Ke, Xiang Fu and Wenhao Hu

J. Am. Chem. Soc., 2025, 147, 19458
DOI: 10.1021/jacs.5c04924

Asymmetric Decarboxylative Protonation and Deuteration of Cyanoacetic Acids Using an Organometallic Proton Shuttle

Wei-Feng Zheng, Guozhen Wu, Min Hou, Ke Li, Xiaotian Qi and Zhongxing Huang

J. Am. Chem. Soc., 2026, 148, 20985
DOI: 10.1021/jacs.6c05281

Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation

Bo Yang, Shi-Jun Li, Yongdong Wang, Yu Lan and Shifa Zhu

Nat Commun, 2021, 12
DOI: 10.1038/s41467-021-25594-4

Recent advances in transition-metal-catalyzed asymmetric reactions of diazo compounds with electron-rich (hetero-) arenes

Yi-Pan Li, Zi-Qi Li and Shou-Fei Zhu

Tetrahedron Letters, 2018, 59, 2307
DOI: 10.1016/j.tetlet.2018.04.055

Highly efficient chemoselective N-tert butoxycarbonylation of aliphatic/aromatic/heterocyclic amines using diphenylglycoluril as organocatalyst

Amardeep Awasthi, Anagh Mukherjee, Mandeep Singh, Garima Rathee, Kumar Vanka and Ramesh Chandra

Tetrahedron, 2020, 76, 131223
DOI: 10.1016/j.tet.2020.131223

Cu-Catalyzed Asymmetric Carbene Insertion into N–H, O–H, and S–H Bonds: Challenging the Existing Mechanistic Dogma

Arushi Tyagi, Kriti Gupta and Garima Jindal

JACS Au, 2025, 5, 4879
DOI: 10.1021/jacsau.5c00807

Enantioselective synthesis of amino acids from ammonia

Mao-Lin Li, Jia-Bin Pan and Qi-Lin Zhou

Nat Catal, 2022, 5, 571
DOI: 10.1038/s41929-022-00779-2

Rhodium(I)-Catalyzed O–H Insertions onO-Protected α-Diazo-β-Hydroxyesters

Ophélie Montiège, Florian Rouzier, Jérôme Lhoste, Catherine Gaulon-Nourry, Anne-Sophie Castanet and Anne-Caroline Chany

J. Org. Chem., 2024, 89, 3194
DOI: 10.1021/acs.joc.3c02652

Dual-function enzyme catalysis for enantioselective carbon–nitrogen bond formation

Zhen Liu, Carla Calvó-Tusell, Andrew Z. Zhou, Kai Chen, Marc Garcia-Borràs and Frances H. Arnold

Nat. Chem., 2021, 13, 1166
DOI: 10.1038/s41557-021-00794-z

Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy

Linxuan Li, Xinyu Zhang, Yongquan Ning, Xiaolong Zhang, Binbin Liu, Zhansong Zhang, Paramasivam Sivaguru, Giuseppe Zanoni, Shuang Li, Edward A. Anderson and Xihe Bi

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-31976-z

Cu/PCy3‐Catalyzed Formal Carbene Insertion into Electron‐Deficient C−H Bonds

Yuan‐Yuan Ren, Hong‐Xiang Mao, Meng‐Yang Hu, Shou‐Fei Zhu and Qi‐Lin Zhou

ChemCatChem, 2020, 12, 4267
DOI: 10.1002/cctc.202000684

Catalyst‐ and Light‐free S−H Insertion between Phosphorodithioic Acids and Diazo Compounds: Rapid Access to Dialkylphosphorodithioates

Meiling Huang, Zi Ye, Weici Xu and Ming‐Hua Xu

Asian J Org Chem, 2023, 12
DOI: 10.1002/ajoc.202300053

Rh(III)-Catalyzed Aminoalkylation of Alkenes with Diazo Compounds toward Functionalized Isoindolinones

Yuying Liu, Zhanwei Fu, Chao Yang, Mupeng Luo, Shurong Ban and Shouguo Wang

Chinese Journal of Organic Chemistry, 2024, 44, 3505
DOI: 10.6023/cjoc202405016

Enantioselective synthesis of chiral amides by carbene insertion into amide N–H bond

Xuan-Ge Zhang, Zhi-Chun Yang, Jia-Bin Pan, Xiao-Hua Liu and Qi-Lin Zhou

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-48266-5

Relay Catalysis by Achiral Borane and Chiral Phosphoric Acid in the Metal-Free Asymmetric Hydrogenation of Chromones

Jingjing Chen, Bochao Gao, Xiangqing Feng, Wei Meng and Haifeng Du

Org. Lett., 2021, 23, 8565
DOI: 10.1021/acs.orglett.1c03286

A Spiro Phosphamide Catalyzed Enantioselective Proton Transfer of Ylides in a Free Carbene Insertion into N−H Bonds

Jia‐Bin Pan, Xuan‐Ge Zhang, Yi‐Fan Shi, Ai‐Cui Han, Yu‐Jia Chen, Jing Ouyang, Mao‐Lin Li and Qi‐Lin Zhou

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202300691

Asymmetric Photocatalytic C(sp3)–H Bond Addition to α-Substituted Acrylates

Zhen-Yao Dai, Zhong-Sheng Nong, Shun Song and Pu-Sheng Wang

Org. Lett., 2021, 23, 3157
DOI: 10.1021/acs.orglett.1c00801

Visible-light-mediated catalytic asymmetric synthesis of α-amino esters via free carbene insertion into N H bond

Ying Zhou, Yan Zhang, Canghai Yu, Xin Yue, Feng Jiang and Wengang Guo

Tetrahedron Letters, 2023, 122, 154496
DOI: 10.1016/j.tetlet.2023.154496

Visible-Light-Promoted Site-Selective N1-Alkylation of Benzotriazoles with α-Diazoacetates

Jingya Yang, Jiaokui Duan, Ganggang Wang, Hongyan Zhou, Ben Ma, Chengqi Wu and Jianliang Xiao

Org. Lett., 2020, 22, 7284
DOI: 10.1021/acs.orglett.0c02619

Enantioselective Oxidative Cyclization/Mannich Addition Enabled by Gold(I)/Chiral Phosphoric Acid Cooperative Catalysis

Hanlin Wei, Ming Bao, Kuiyong Dong, Lihua Qiu, Bing Wu, Wenhao Hu and Xinfang Xu

Angewandte Chemie, 2018, 130, 17446
DOI: 10.1002/ange.201812140

The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2018

James W. Herndon

Coordination Chemistry Reviews, 2019, 401, 213051
DOI: 10.1016/j.ccr.2019.213051

Geminal Aminocyanation Enabled by Ylide Mediated Rearrangement

Zichun Yan, Meirong Huang, Chuang Wang, Xinhao Zhang, Shengbiao Tang and Jiangtao Sun

Org. Lett., 2024, 26, 10273
DOI: 10.1021/acs.orglett.4c03797

Dealuminated H–Y zeolites generate, stabilize and catalytically insert carbenes from diazocarbonyl compounds

Yongkun Zheng, Miguel Espinosa, Marta Mon and Antonio Leyva–Pérez

Journal of Catalysis, 2024, 440, 115835
DOI: 10.1016/j.jcat.2024.115835

Asymmetric N‐Alkylation of 1H‐Indoles via Carbene Insertion Reaction

Quanxin Peng, Meirong Huang, Guangyang Xu, Yan Zhu, Ying Shao, Shengbiao Tang, Xinhao Zhang and Jiangtao Sun

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202313091

Intramolecular proton transfer in the isomerization of hydroxyacetone: Characterization based on reaction force analysis and the bond fragility spectrum

Huiet V. Joseph and Wallace D. Derricotte

Int J of Quantum Chemistry, 2020, 120
DOI: 10.1002/qua.26269

Enantioselective three-component aminomethylation of α-diazo ketones with alcohols and 1,3,5-triazines

Jiuwei Che, Li Niu, Shikun Jia, Dong Xing and Wenhao Hu

Nat Commun, 2020, 11
DOI: 10.1038/s41467-020-15345-2

Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E−H Bonds

Nikita M. Ankudinov, Denis A. Chusov, Yulia V. Nelyubina and Dmitry S. Perekalin

Angew Chem Int Ed, 2021, 60, 18712
DOI: 10.1002/anie.202105179

Asymmetric Dearomatization of Indoles with Azodicarboxylates via Cascade Electrophilic Amination/Aza-Prins Cyclization/Phenonium-like Rearrangement

Xian-Yun Huang, Pei-Pei Xie, Lei-Ming Zou, Chao Zheng and Shu-Li You

J. Am. Chem. Soc., 2023, 145, 11745
DOI: 10.1021/jacs.3c02773

Engineering metalloenzymes for new-to-nature carbene and nitrene transfer biocatalysis

Wenjin Pan, Xinlong Fan, Wantong Jiang, Sirui Xin, Ningzhi Wang, Qian Wang, Keyang Yu and Xinkun Ren

Chinese Journal of Catalysis, 2025, 72, 4
DOI: 10.1016/S1872-2067(25)64659-6

Highly Enantioselective Brønsted Acid Catalyzed Heyns Rearrangement

Jin Cao, Yu‐Xuan Su, Xin‐Yu Zhang and Shou‐Fei Zhu

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202212976

Enantioselective Copper-Catalyzed N–H Insertion Reaction of Pyrazoles and α-Diazo Phosphates

Lewan Li, Mengxiang Luo, Yuqing Zhang, Huan Li, Xuyang Gong, Ruiqi Liao, Huaiyu Huang, Xiaoqiong Fu, Jian Lv, Shuangxi Gu and Haifeng Wang

Org. Lett., 2025, 27, 12735
DOI: 10.1021/acs.orglett.5c03859

Enantioselective Synthesis of α-Oxygenated Ketones via Organocatalytic Formal O–H Bond Insertion of Sulfonium Ylides

Chenxiao Qian, Ziwei Zhong, Qingzheng Xu, Pengfei Li, Chaoshen Zhang and Jianwei Sun

J. Am. Chem. Soc., 2025, 147, 32110
DOI: 10.1021/jacs.5c10842

Silver(I)/Dirhodium(II) Catalytic Platform for Asymmetric N–H Insertion Reaction of Heteroaromatics

Shingo Harada, Shumpei Hirose, Mizuki Takamura, Maika Furutani, Yuna Hayashi and Tetsuhiro Nemoto

J. Am. Chem. Soc., 2024, 146, 733
DOI: 10.1021/jacs.3c10596

Prediction of acid pKa values in the solvent acetone based on COSMO‐RS

Niklas Sülzner, Julia Haberhauer, Christof Hättig and Arnim Hellweg

J Comput Chem, 2022, 43, 1011
DOI: 10.1002/jcc.26864

Enantioselective Intermolecular Mannich-Type Interception of Phenolic Oxonium Ylide for the Direct Assembly of Chiral 2,2-Disubstituted Dihydrobenzofurans

Kemiao Hong, Shanliang Dong, Xinxin Xu, Zhijing Zhang, Taoda Shi, Haoxuan Yuan, Xinfang Xu and Wenhao Hu

ACS Catal., 2021, 11, 6750
DOI: 10.1021/acscatal.1c01321

Ammonia to chiral α-amino acid

Liangliang Yang and Jianwei Sun

Nat Catal, 2022, 5, 471
DOI: 10.1038/s41929-022-00811-5

Visible Light Induced B–H Bond Insertion Reaction with Diazo Compounds

Mingjun Yi, Xiaoyu Wu, Liqun Yang, Yao Yuan, Yan Lu and Zhaoguo Zhang

J. Org. Chem., 2024, 89, 12583
DOI: 10.1021/acs.joc.4c01510

Palladium‐Catalyzed Enantioselective Thiocarbonylation of Styrenes

Xihong Wang, Bing Wang, Xuemei Yin, Wangzhi Yu, Yang Liao, Jialin Ye, Min Wang, Lianrui Hu and Jian Liao

Angewandte Chemie, 2019, 131, 12392
DOI: 10.1002/ange.201905905

Enantioselective Synthesis of Chiral Amines via Biocatalytic Carbene N–H Insertion

Viktoria Steck, Daniela M. Carminati, Nathan R. Johnson and Rudi Fasan

ACS Catal., 2020, 10, 10967
DOI: 10.1021/acscatal.0c02794

Tropylium-Catalyzed O–H Insertion Reactions of Diazoalkanes with Carboxylic Acids

Claire Empel, Thanh Vinh Nguyen and Rene M. Koenigs

Org. Lett., 2021, 23, 548
DOI: 10.1021/acs.orglett.0c04069

Visible-Light-Promoted N-Alkylation Reactions of (aza)Aromatic Amines with Ethyl Diazoacetate

Yating Zhao, Fan Liu, Qiuan Wang and Wujiong Xia

Acta Chimica Sinica, 2023, 81, 111
DOI: 10.6023/A22120490

Privilege-Structure-Oriented Three-Component Asymmetric Aminomethylation: Assembly of Chiral 3-Aminomethyl Indolones

Zhenghui Kang, Dan Zhang, Xinfang Xu and Wenhao Hu

Org. Lett., 2019, 21, 9878
DOI: 10.1021/acs.orglett.9b03787

Highly Enantioselective O–H Bond Insertion Reaction of α-Alkyl- and α-Alkenyl-α-diazoacetates with Water

You Li, Yu-Tao Zhao, Ting Zhou, Meng-Qing Chen, Yi-Pan Li, Ming-Yao Huang, Zhen-Chuang Xu, Shou-Fei Zhu and Qi-Lin Zhou

J. Am. Chem. Soc., 2020, 142, 10557
DOI: 10.1021/jacs.0c04532

Enantioselective N–H Bond Insertion Reaction of Anilines Enabled by Ruthenium and Chiral Phosphoric Acid Cooperative Catalysis

Shaoran An, Yan Zhu and Jiangtao Sun

Org. Lett., 2024, 26, 6214
DOI: 10.1021/acs.orglett.4c02135

TfOH-Catalyzed N–H Insertion of α-Substituted-α-Diazoesters with Anilines Provides Access to Unnatural α-Amino Esters

Sha Hu, Jiale Wu, Zuolin Lu, Jiaqi Wang, Yuan Tao, Meifen Jiang and Fener Chen

J. Org. Chem., 2021, 86, 3223
DOI: 10.1021/acs.joc.0c02588

Copper‐Catalyzed Si—H Bond Insertion Polymerization for Synthesis of Optically Active Polyesters Containing Silicon

Xiao‐Yong Zhai, Xiao‐Qing Wang, Bo Wu and Yong‐Gui Zhou

Chin. J. Chem., 2022, 40, 21
DOI: 10.1002/cjoc.202100569

Chemo‐ and Enantioselective Insertion of Furyl Carbene into the N−H Bond of 2‐Pyridones

Kai Wang, Ziye Liu, Guangyang Xu, Ying Shao, Shengbiao Tang, Ping Chen, Xinhao Zhang and Jiangtao Sun

Angew Chem Int Ed, 2021, 60, 16942
DOI: 10.1002/anie.202104708

Copper‐Catalyzed Cross‐Coupling Reaction of α‐Halo‐N‐Tosylhydrazones with H‐Phosphoryl Compounds to Afford Alkenylphosphoryl Compounds

Ruwei Shen, Kaixin Yin and Yishuai Fan

Asian J Org Chem, 2023, 12
DOI: 10.1002/ajoc.202200665

Chiral Proton-Transfer Shuttle Catalysts Promoted Enantioselective Nazarov Cyclization

Jin Cao and Shou-Fei Zhu

Synlett, 2023, 34, 29
DOI: 10.1055/a-1967-1175

Engineered Leghemoglobin as a High-Performance Biocatalyst for Carbene N–H Insertion: Active-Site Remodeling Unlocks Catalytic Proficiency

Hong Zhang, Meijiao Gao, Xin Zhang and Zhi Wang

Catalysts, 2025, 15, 950
DOI: 10.3390/catal15100950

Advancements in Gold‐Catalyzed Cascade Reactions to Access Carbocycles and Heterocycles: An Overview

T. Ghosh and S. Bhakta

The Chemical Record, 2023, 23
DOI: 10.1002/tcr.202200225

Light-Mediated Asymmetric Aliphatic C–H Alkylation with Hydrogen Atom Transfer Catalyst and Chiral Phosphoric Acid

Zhen-Yao Dai, Zhong-Sheng Nong and Pu-Sheng Wang

ACS Catal., 2020, 10, 4786
DOI: 10.1021/acscatal.0c00610

Enantioselective Synthesis of Chiral Amides by a Phosphoric Acid Catalyzed Asymmetric Wolff Rearrangement**

Jia‐Bin Pan, Zhi‐Chun Yang, Xuan‐Ge Zhang, Mao‐Lin Li and Qi‐Lin Zhou

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202308122

Rhodium-Catalyzed Formal C–O Insertion in Carbene/Alkyne Metathesis Reactions: Synthesis of 3-Substituted 3H-Indol-3-ols

Shikun Jia, Guizhi Dong, Chaoqun Ao, Xianxing Jiang and Wenhao Hu

Org. Lett., 2019, 21, 4322
DOI: 10.1021/acs.orglett.9b01492

Succinimide-Promoted Malonylamination of Alkenes with Amines and Iodonium Ylides via Trapping of Transient Aminium Radical Cations

Liang Zhang, Xiangjin Kong, Shuya Liu, Zhiguo Zhao, Qun Yu, Wei Wang and Yao Wang

Org. Lett., 2019, 21, 2923
DOI: 10.1021/acs.orglett.9b00983

Asymmetric N‐Alkylation of 1H‐Indoles via Carbene Insertion Reaction

Quanxin Peng, Meirong Huang, Guangyang Xu, Yan Zhu, Ying Shao, Shengbiao Tang, Xinhao Zhang and Jiangtao Sun

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202313091

Histidine Proton Shuttle-Initiated Switchable Inversion of Circularly Polarized Luminescence

Dian Niu, Lukang Ji, Guanghui Ouyang and Minghua Liu

ACS Appl. Mater. Interfaces, 2020, 12, 18148
DOI: 10.1021/acsami.0c02080

Efficient Synthesis of Diaryl Quaternary Centers by Rh(II)/Xantphos Catalyzed Relay C−H Functionalization and Allylic Alkylation

Zhaoliang Ge, Bin Lu, Huailong Teng and Xiaoming Wang

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202202820

P(III)-Mediated Formal Reductive N–H Bond Insertion Reaction of Hydrazones to α-Keto Esters

Norihiko Takeda, Tomoki Miyashita, Naoya Hirokawa, Motohiro Yasui and Masafumi Ueda

Chem. Pharm. Bull., 2024, 72, 413
DOI: 10.1248/cpb.c24-00091

Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E−H Bonds

Nikita M. Ankudinov, Denis A. Chusov, Yulia V. Nelyubina and Dmitry S. Perekalin

Angewandte Chemie, 2021, 133, 18860
DOI: 10.1002/ange.202105179

Enantioselective formal carbene insertion into C–N bond of aminal as a concise track to chiral α-amino-β2,2-amino acids and synthetic applications

Xue Tian, Xinfang Xu, Tongfei Jing, Zhenghui Kang and Wenhao Hu

Green Synthesis and Catalysis, 2021, 2, 337
DOI: 10.1016/j.gresc.2021.10.007

Atroposelective Synthesis of N-Arylindoles via Enantioselective N–H Bond Insertion

Chao Niu, Yi Zhou, Qiang Chen, Yan Zhu, Shengbiao Tang, Zhi-Xiang Yu and Jiangtao Sun

Org. Lett., 2022, 24, 7428
DOI: 10.1021/acs.orglett.2c03003

Access to Syn α‐Amino‐β‐Hydroxyesters by N−H Insertion on O‐Protected α‐Diazo‐β‐Hydroxyesters

Thomas Defuentes, Jérôme Lhoste, Catherine Gaulon‐Nourry, Anne‐Sophie Castanet and Anne‐Caroline Chany

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202400539

Asymmetric Hydrogenation by Relay Catalysis with FLPs and CPAs: Stereodivergent Synthesis of 3-Substituted Flavanones

Jingjing Chen, Wei Meng, Xiangqing Feng and Haifeng Du

J. Org. Chem., 2022, 87, 10544
DOI: 10.1021/acs.joc.2c01278

Annulative Coupling of o-Phenylenediamine and Diazo Esters: Access to 3-Arylquinoxaline-2-ones

Trayambek Nath Chaubey and Satyendra Kumar Pandey

J. Org. Chem., 2026, 91, 6901
DOI: 10.1021/acs.joc.6c00265

Formaldehyde-Mediated Hydride Liberation of Alkylamines for Intermolecular Reactions in Hexafluoroisopropanol

Shaokun Cai, Hong Tang, Bo Li, Yingbo Shao, Danqi Zhang, Hanliang Zheng, Tianjiao Qiao, Xin Chu, Gang He, Xiao-Song Xue and Gong Chen

J. Am. Chem. Soc., 2024, 146, 5952
DOI: 10.1021/jacs.3c12215

A Powerful Chiral Super Brønsted C–H Acid for Asymmetric Catalysis

Bingfei Peng, Jiguo Ma, Jianhua Guo, Yating Gong, Ronghao Wang, Yi Zhang, Jinlong Zeng, Wen-Wen Chen, Kuiling Ding and Baoguo Zhao

J. Am. Chem. Soc., 2022, 144, 2853
DOI: 10.1021/jacs.1c12723

From Radical Coupling to Enantioselective Controlled Protonation: Advancing Precise Construction of Stereocenters

Xin Sun, Wenle Zhu, Yanli Yin, Xiaowei Zhao and Zhiyong Jiang

J. Am. Chem. Soc., 2025, 147, 4382
DOI: 10.1021/jacs.4c15276

Copper‐Catalyzed Highly Enantioselective Ring‐Opening/Cyclopropanation of 1‐Silylcyclopropenes

Xiao‐Shuai Wen, Zhang‐Wei Wang, Jia‐Bao Zhao, Han‐Chu Zhang, Ming‐Yao Huang and Shou‐Fei Zhu

Chin. J. Chem., 2025, 43, 2097
DOI: 10.1002/cjoc.70100

Highly enantioselective carbene insertion into N–H bonds of aliphatic amines

Mao-Lin Li, Jin-Han Yu, Yi-Hao Li, Shou-Fei Zhu and Qi-Lin Zhou

Science, 2019, 366, 990
DOI: 10.1126/science.aaw9939

Chiral NCN Pincer Iridium(III) Complexes with Bis(imidazolinyl)phenyl Ligands: Synthesis and Application in Enantioselective C–H Functionalization of Indoles with α-Aryl-α-diazoacetates

Nan Li, Wen-Jing Zhu, Juan-Juan Huang, Xin-Qi Hao, Jun-Fang Gong and Mao-Ping Song

Organometallics, 2020, 39, 2222
DOI: 10.1021/acs.organomet.0c00174

Transition Metal‐Catalyzed Carbene Coupling Reaction

Ying Li, Ze Li, Shufeng Chen and Jianbo Wang

Chin. J. Chem., 2026, 44, 1258
DOI: 10.1002/cjoc.70463

Pd/BINAP/Peroxide‐Enabled Relay Multicomponent Reactions

Yan‐Nian Pan, Cheng‐Kai Yuan, Zhen‐Chun Li and Yi Lu

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.70050

Cu-Catalyzed Cross-Electrophilic Coupling of α-Diazoesters with O-Benzoyl Hydroxylamines for the Synthesis of Unnatural N-Alkyl α-Amino Acid Derivatives

Yiu-Wai Yeung, Chun-Ming Chan, Yu-Ting Chen, Marco Chan, Mingyu Luo, Xin Gao, Bingnan Du and Wing-Yiu Yu

Org. Lett., 2023, 25, 619
DOI: 10.1021/acs.orglett.2c04161

Enantioselective Oxidative Cyclization/Mannich Addition Enabled by Gold(I)/Chiral Phosphoric Acid Cooperative Catalysis

Hanlin Wei, Ming Bao, Kuiyong Dong, Lihua Qiu, Bing Wu, Wenhao Hu and Xinfang Xu

Angew Chem Int Ed, 2018, 57, 17200
DOI: 10.1002/anie.201812140

Axial Ligand Enables Synthesis of Allenylsilane through Dirhodium(II) Catalysis

Wendeng Li, Rui Wu, Hao Ruan, Bo Xiao, Xiang Gao, Huanfeng Jiang, Kai Chen, Tian‐Yu Sun and Shifa Zhu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202409332

Enantioselective Synthesis of Chiral Amides by a Phosphoric Acid Catalyzed Asymmetric Wolff Rearrangement**

Jia‐Bin Pan, Zhi‐Chun Yang, Xuan‐Ge Zhang, Mao‐Lin Li and Qi‐Lin Zhou

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202308122

Photoredox Catalysis of Aromatic β‐Ketoesters for in Situ Production of Transient and Persistent Radicals for Organic Transformation

Xiu‐Long Yang, Jia‐Dong Guo, Hongyan Xiao, Ke Feng, Bin Chen, Chen‐Ho Tung and Li‐Zhu Wu

Angewandte Chemie, 2020, 132, 5403
DOI: 10.1002/ange.201916423

Synthesis of Biphenanthrol-Based Confined Chiral Phosphoric Acid

Shouyi Cen and Zhipeng Zhang

Chinese Journal of Organic Chemistry, 2022, 42, 2574
DOI: 10.6023/cjoc202203019

Blue Light‐Promoted N−H Insertion of Carbazoles, Pyrazoles and 1,2,3‐Triazoles into Aryldiazoacetates

Mateus L. Stivanin, Alessandra A. G. Fernandes, Amanda F. da Silva, Celso Y. Okada and Igor D. Jurberg

Adv Synth Catal, 2020, 362, 1106
DOI: 10.1002/adsc.201901343

Blue light-promoted N–H insertion of amides, isatins, sulfonamides and imides into aryldiazoacetates: Synthesis of unnatural α-aryl amino acid derivatives

Celso Y. Okada, Caio Y. dos Santos and Igor D. Jurberg

Tetrahedron, 2020, 76, 131316
DOI: 10.1016/j.tet.2020.131316

Asymmetric Arylation of Diazoesters with Anisoles Enabled by Cooperative Gold and Phosphoric Acid Catalysis

Guangyang Xu, Meirong Huang, Tao Zhang, Ying Shao, Shengbiao Tang, He Cao, Xinhao Zhang and Jiangtao Sun

Org. Lett., 2022, 24, 2809
DOI: 10.1021/acs.orglett.2c00709