Issue 11, 2022

Novel class of organic crystal scintillators based on aggregation-induced emission

Abstract

Herein, we synthesized 1,1,2,3,4,5-hexaphenyl-1H-silole (HPS) crystals to develop organic crystal scintillators based on aggregation-induced emission (AIE). The scintillation properties of HPS crystals were characterized. An emission peak at approximately 490 nm was observed in photoluminescence emission and X-ray-excited radioluminescence spectra. The scintillation decay time constants were 5.4, and 21 ns. HPS crystals exhibited light yields of 3100 photons/5.5 MeV and 11 000 photons/MeV under α-ray and X-ray irradiation, respectively. The light yield and scintillation decay time of HPS crystals are comparable to those of conventional organic crystal scintillators, indicating the suitability of such organic crystals as scintillation materials based on AIE behavior.

Graphical abstract: Novel class of organic crystal scintillators based on aggregation-induced emission

Supplementary files

Article information

Article type
Research Article
Submitted
02 mar 2022
Accepted
09 maj 2022
First published
16 maj 2022

Mater. Chem. Front., 2022,6, 1470-1476

Novel class of organic crystal scintillators based on aggregation-induced emission

A. Sato, M. Koshimizu, Y. Fujimoto, S. Komatsuzaki, S. Kishimoto and K. Asai, Mater. Chem. Front., 2022, 6, 1470 DOI: 10.1039/D2QM00187J

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