Issue 13, 2022

In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

Abstract

Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields.

Graphical abstract: In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

Supplementary files

Article information

Article type
Communication
Submitted
12 nov 2021
Accepted
17 jan 2022
First published
17 jan 2022

Chem. Commun., 2022,58, 2124-2127

In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

V. Liautard, M. Delgado, B. Colin, L. Chabaud, G. Michaud and M. Pucheault, Chem. Commun., 2022, 58, 2124 DOI: 10.1039/D1CC06390A

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