Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

Alexandra Hicken; Andrew J. P. White; Mark R. Crimmin

doi:10.1039/C8DT01569D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes†

Alexandra Hicken,

^ab Andrew J. P. White^b and Mark R. Crimmin

*^b

Author affiliations

* Corresponding authors

^a SSCP DTP, Grantham Institute, Imperial College London, South Kensington, London, UK

^b Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: m.crimmin@imperial.ac.uk

Abstract

The preparation and structural characterisation of three new heterobimetallic hydride complexes containing 3-centre,2-electron W–H–Cu bonds is reported. These complexes have been characterised by single crystal X-ray crystallography and multinuclear NMR spectroscopy. The bonding in these complexes has been analysed by DFT calculations.

This article is part of the themed collections: Celebrating our 2020 Prize and Award winners and New Talent: Europe

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8DT01569D
Article type: Paper
Submitted: 20 apr 2018
Accepted: 11 maj 2018
First published: 14 maj 2018

Download Citation

Dalton Trans., 2018,47, 10595-10600

Permissions

Request permissions

Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

A. Hicken, A. J. P. White and M. R. Crimmin, Dalton Trans., 2018, 47, 10595 DOI: 10.1039/C8DT01569D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions

Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Preparation and characterisation of heterobimetallic copper–tungsten hydride complexes

Social activity

Search articles by author

Spotlight

Advertisements