Issue 13, 2015

A family of 3D lanthanide organic frameworks with tunable luminescence and slow magnetic relaxation

Abstract

A family of 3D lanthanide organic frameworks with 5-(pyridin-4-yl)isophthalic acid (H2PIP), formulated as [Ln2(PIP)3(H2O)4]·2DMF·3H2O (Ln = Sm 1, Eu 2, Gd 3, Tb 4, Dy 5 and Ho 6) have been synthesized and structurally characterized. They are isomorphous and feature a 3D 6-connected pcu topology. The tunable luminescence of 2 and 4 is investigated by changing the temperature and the variation of excitation wavelength. In addition, the slow magnetic relaxation behavior is observed in 5.

Graphical abstract: A family of 3D lanthanide organic frameworks with tunable luminescence and slow magnetic relaxation

Supplementary files

Article information

Article type
Paper
Submitted
20 nov 2014
Accepted
06 jan 2015
First published
07 jan 2015

RSC Adv., 2015,5, 9898-9903

Author version available

A family of 3D lanthanide organic frameworks with tunable luminescence and slow magnetic relaxation

Q. Li and S. Du, RSC Adv., 2015, 5, 9898 DOI: 10.1039/C4RA14939D

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