Synthesis of a new endohedral fullerene family, Sc2S@C2n (n = 40–50) by the introduction of SO2

Ning Chen; Manuel N. Chaur; Cheryl Moore; Julio R. Pinzón; Ramon Valencia; Antonio Rodríguez-Fortea; Josep M. Poblet; Luis Echegoyen

doi:10.1039/C0CC00835D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Synthesis of a new endohedral fullerene family, Sc₂S@C_2n (n = 40–50) by the introduction of SO₂†‡

Ning Chen,^a Manuel N. Chaur,^a Cheryl Moore,^a Julio R. Pinzón,^a Ramon Valencia,^b Antonio Rodríguez-Fortea,^b Josep M. Poblet*^b and Luis Echegoyen*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Clemson University, 219 Hunter Laboratories, Clemson, USA
E-mail: luis@clemson.edu
Fax: +1 864-656-6613

^b Department de Química Fisica i Inorgànica, Universitat Rovira y Virgilic/Marcel lí Domingo s/n, Campus Sescelades, E-43007 Tarragona, Spain
E-mail: josepmaria.poblet@urv.cat
Fax: +34 977-559-563

Abstract

By introducing SO₂ as the sulfur source, the synthesis of an extensive family of cluster endohedral fullerenes Sc₂S@C_2n (n = 40–50) was demonstrated and a new isomer of Sc₂S@C₈₂ (C_s : 6) was isolated and characterized by spectroscopic and electrochemical methods for the first time.

This article is part of the themed collection: Carbon nanostructures

Download options Please wait...

Supplementary files

Experimental details, HPLC chromatogram of raw extract, EDS spectra of Sc₂S@C₈₂ (I) and (II). Mass spectra of the first and second fraction from HPLC. Calculation results of EC and HOMO–LUMO gap. XYZ coordinates of computed structures PDF (464K)

Article information

DOI: https://doi.org/10.1039/C0CC00835D
Article type: Communication
Submitted: 09 apr 2010
Accepted: 07 maj 2010
First published: 25 maj 2010

Download Citation

Chem. Commun., 2010,46, 4818-4820

Permissions

Request permissions

Synthesis of a new endohedral fullerene family, Sc₂S@C_2n (n = 40–50) by the introduction of SO₂

N. Chen, M. N. Chaur, C. Moore, J. R. Pinzón, R. Valencia, A. Rodríguez-Fortea, J. M. Poblet and L. Echegoyen, Chem. Commun., 2010, 46, 4818 DOI: 10.1039/C0CC00835D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications