Issue 3, 2006

Solvent-free synthesis of a microporous metal–organic framework

Abstract

We describe the first solvent-free mechanochemical synthesis of a microporous metal–organic framework [Cu(INA)2] (INA = isonicotinic acid); the product has robust 3-dimensional connectivity and is obtained quantitatively by grinding together copper acetate and isonicotinic acid for 10 minutes without any applied heating—the high efficiency of the synthesis suggests that mechanochemical synthesis should be further investigated as a convenient method for the preparation of microporous metal–organic frameworks (MOFs).

Graphical abstract: Solvent-free synthesis of a microporous metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
28 sep 2005
Accepted
25 jan 2006
First published
06 feb 2006

CrystEngComm, 2006,8, 211-214

Solvent-free synthesis of a microporous metal–organic framework

A. Pichon, A. Lazuen-Garay and S. L. James, CrystEngComm, 2006, 8, 211 DOI: 10.1039/B513750K

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