Issue 4, 2022

A nickel/organoboron catalyzed metallaphotoredox platform for C(sp2)–P and C(sp2)–S bond construction

Abstract

Herein, an organoboron photocatalyst, aminoquinolate diarylboron (AQDAB), is utilized collaboratively with a nickel catalyst in metallaphotoredox catalyzed C(sp2)–P and C(sp2)–S cross-coupling reactions. This strategy effectively couples aryl halides with diarylphosphine oxides and thiols at room temperature under an air atmosphere, affording the corresponding triarylphosphine oxides and thioethers in generally moderate to good yields.

Graphical abstract: A nickel/organoboron catalyzed metallaphotoredox platform for C(sp2)–P and C(sp2)–S bond construction

Supplementary files

Article information

Article type
Research Article
Submitted
25 nov 2021
Accepted
06 jan 2022
First published
07 jan 2022

Org. Chem. Front., 2022,9, 1070-1076

A nickel/organoboron catalyzed metallaphotoredox platform for C(sp2)–P and C(sp2)–S bond construction

Y. Zhu, W. Zu, Q. Tian, Z. Cao, Y. Wei and L. Xu, Org. Chem. Front., 2022, 9, 1070 DOI: 10.1039/D1QO01778K

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