Oxygen vacancies on Nb2O5 enhanced the performance of H2O2 electrosynthesis from O2 reduction

Xiaoge Peng; Shijie Zhang; Zhikang Bao; Lei Ding; Guoliang Wang; Yizhen Shao; Zaixiang Xu; Wenkai Ji; Ge Feng; Shibin Wang; Xing Zhong; Jianguo Wang

doi:10.1039/D2CC02577A

Oxygen vacancies on Nb₂O₅ enhanced the performance of H₂O₂ electrosynthesis from O₂ reduction†

Xiaoge Peng,‡^a Shijie Zhang,‡^a Zhikang Bao,^a Lei Ding,^a Guoliang Wang,^a Yizhen Shao,^a Zaixiang Xu,^a Wenkai Ji,^a Ge Feng,^a Shibin Wang,^a Xing Zhong

^a and Jianguo Wang

*^a

Author affiliations

* Corresponding authors

^a Institute of Industrial Catalysis, College of Chemical Engineering, State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou, China
E-mail: jgw@zjut.edu.cn

Abstract

A serial oxygen vacancy (O_V) on Nb₂O₅ is synthesised by H₂ calcination, and H-300 exhibited high selectivity and activity for H₂O₂ (93.4%, 562.5 mmol g_cat⁻¹). A volcano relationship is identified between the O_V content and performance, which provides an attractive insight into designing electrocatalysts.

This article is part of the themed collection: Electrochemical Energy

Chemical Communications

Oxygen vacancies on Nb₂O₅ enhanced the performance of H₂O₂ electrosynthesis from O₂ reduction†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Oxygen vacancies on Nb₂O₅ enhanced the performance of H₂O₂ electrosynthesis from O₂ reduction

Social activity

Search articles by author

Spotlight

Advertisements

Chemical Communications