Issue 33, 2021

The hydroboration of α-diimines

Abstract

The uncatalyzed addition of catecholborane to α-diimines has been examined. Reactions proceed smoothly at room temperature in the absence of a catalyst or additive, providing bis-hydroboration products with 3-coordinate boron centres or mono-hydroboration products with 4-coordinate boron centres, depending on the nature of the diimine reagent.

Graphical abstract: The hydroboration of α-diimines

Supplementary files

Article information

Article type
Communication
Submitted
01 mar 2021
Accepted
13 apr 2021
First published
15 apr 2021

New J. Chem., 2021,45, 14908-14912

The hydroboration of α-diimines

S. J. Geier, J. F. Binder, C. M. Vogels, L. K. Watanabe, C. L. B. Macdonald and S. A. Westcott, New J. Chem., 2021, 45, 14908 DOI: 10.1039/D1NJ01025E

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