Issue 33, 2021

Li deposited on LiCl: an efficient reducing agent

Abstract

Lithium was deposited onto lithium chloride powder in a ∼5% weight/weight ratio. This material serves as a source of elemental lithium with benefits over bulk lithium alternatives including increased mass to facilitate measurement for small scale reactions and increased surface area. The Li/LiCl material is applied in the synthesis of a dilithiobutadienide that is transformed into a stannole with a drastic decrease in reaction time and notable increase in yield over commercial lithium granules.

Graphical abstract: Li deposited on LiCl: an efficient reducing agent

Supplementary files

Article information

Article type
Communication
Submitted
26 feb 2020
Accepted
30 mar 2020
First published
31 mar 2020

New J. Chem., 2021,45, 14913-14915

Li deposited on LiCl: an efficient reducing agent

X. Su, L. E. Laperriere and C. D. Martin, New J. Chem., 2021, 45, 14913 DOI: 10.1039/D0NJ01010C

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