Issue 6, 2020

Recent progress in C(aryl)–C(alkyl) bond cleavage of alkylarenes

Abstract

Cleavage of the C(aryl)–C(alkyl) σ-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However, C(aryl)–C(alkyl) bonds of alkylarenes remain intact under most conventional reaction conditions. In this review, we highlight the results of recent C(aryl)–C(alkyl) bond cleavages that have been induced by homogeneous transition metal reagents, by oxidative cleavages, and by rearrangement.

Graphical abstract: Recent progress in C(aryl)–C(alkyl) bond cleavage of alkylarenes

Article information

Article type
Review Article
Submitted
03 dec 2019
Accepted
22 feb 2020
First published
26 feb 2020

Org. Chem. Front., 2020,7, 896-904

Recent progress in C(aryl)–C(alkyl) bond cleavage of alkylarenes

P. Dai, H. Wang, X. Cui, J. Qu and Y. Kang, Org. Chem. Front., 2020, 7, 896 DOI: 10.1039/C9QO01438A

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