Issue 18, 2019

Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)] into [(NO)2Fe(η3-HCS2)]via reaction with CS2

Abstract

Reaction of compounds [(NO)2Fe(TMEDA)] and [BH4] affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)2Fe(η2-BH4)] (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS2 into DNIC [(NO)2Fe(η3-HCS2)], the first DNIC featuring both linear/bent NO ligands and Fe 3dz2-to-HCS2 π* backbonding interaction.

Graphical abstract: Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]− into [(NO)2Fe(η3-HCS2)]−via reaction with CS2

Supplementary files

Article information

Article type
Communication
Submitted
29 nov 2018
Accepted
04 jan 2019
First published
05 jan 2019

Dalton Trans., 2019,48, 5897-5902

Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)] into [(NO)2Fe(η3-HCS2)]via reaction with CS2

H. Huang, W. Ching, Y. Tseng, C. Chen and T. Lu, Dalton Trans., 2019, 48, 5897 DOI: 10.1039/C8DT04714F

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