Direct functionalization and Pd-catalyzed cross-coupling of difuryl(supermesityl)borane (1) led to highly emissive organoborane compounds 3 and 4. Photophysical and TD-DFT studies reveal an increase of the HOMO levels with higher hetarene content and stabilization of the HOMO and LUMO levels through B-doping, leading to very robust, air-stable electron-accepting materials.
N. A. Riensch, L. Fritze, T. Schindler, M. Kremer and H. Helten, Dalton Trans., 2018, 47, 10399 DOI: 10.1039/C8DT01716F
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