Volume 198, 2017
From the journal:

Faraday Discussions

Fe, Ru, and Os complexes with the same molecular framework: comparison of structures, properties and catalytic activities†

Masaki Yoshida,‡a   Mio Kondo,*abcd   Masaya Okamura,ae   Mari Kanaike,a   Setsiri Haesuwannakij,abf   Hidehiro Sakuraidf  and  Shigeyuki Masaoka ORCID logo *abc  

* Corresponding authors

a Department of Life and Coordination-Complex Molecular Science, Institute for Molecular Science (IMS), 5-1 Higashiyama, Myodaiji, Okazaki, Aichi 444-8787, Japan
E-mail: mio@ims.ac.jp, masaoka@ims.ac.jp

b SOKENDAI [The Graduate University for Advanced Studies], Shonan Village, Hayama, Kanagawa 240-0193, Japan

c Research Center of Integrative Molecular Systems (CIMoS), Institute for Molecular Science (IMS), 38 Nishigo-naka, Myodaiji, Okazaki, Aichi 444-8585, Japan

d ACT-C, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama, Japan

e Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan

f Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan

Abstract

A series of group 8 metal complexes with the same molecular framework, [M(PY5Me2)L]n+ (M = Fe, Ru, and Os; PY5Me2 = 2,6-bis[1,1-bis(2-pyridyl)ethyl]pyridine; L = monodentate ligand), were successfully synthesized and structurally characterized. The spectroscopic and electrochemical properties as well as the catalytic activity for water oxidation of these complexes were investigated.

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Article information

DOI
https://doi.org/10.1039/C6FD00227G
Article type
Paper
Submitted
02 nov 2016
Accepted
02 dec 2016
First published
02 dec 2016

Faraday Discuss., 2017,198, 181-196

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Fe, Ru, and Os complexes with the same molecular framework: comparison of structures, properties and catalytic activities

M. Yoshida, M. Kondo, M. Okamura, M. Kanaike, S. Haesuwannakij, H. Sakurai and S. Masaoka, Faraday Discuss., 2017, 198, 181 DOI: 10.1039/C6FD00227G

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