Issue 5, 2015

An iodine-promoted Meyer–Schuster rearrangement for the synthesis of α-iodo unsaturated ketones

Abstract

A facile and efficient iodine-promoted Meyer–Schuster rearrangement of propargyl alcohols for the synthesis of α-iodo-α,β-unsaturated ketones is presented. The reaction is concisely conducted at ambient temperature and shows good functional group tolerance.

Graphical abstract: An iodine-promoted Meyer–Schuster rearrangement for the synthesis of α-iodo unsaturated ketones

Supplementary files

Article information

Article type
Research Article
Submitted
06 feb 2015
Accepted
10 mar 2015
First published
13 mar 2015

Org. Chem. Front., 2015,2, 506-509

Author version available

An iodine-promoted Meyer–Schuster rearrangement for the synthesis of α-iodo unsaturated ketones

H. Zhu, M. Fan, D. Yang, X. Wang, S. Ke, C. Zhang and Z. Guan, Org. Chem. Front., 2015, 2, 506 DOI: 10.1039/C5QO00048C

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