Issue 4, 2015

Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4] catalyst

Abstract

A Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using a well-defined aluminum porphyrin catalyst is reported. This reaction shows good functional group tolerance under mild reaction conditions to selectively give methyl ketones in excellent yields.

Graphical abstract: Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4]− catalyst

Supplementary files

Article information

Article type
Research Article
Submitted
12 dec 2014
Accepted
31 jan 2015
First published
16 feb 2015

Org. Chem. Front., 2015,2, 346-349

Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4] catalyst

J. R. Lamb, Y. Jung and G. W. Coates, Org. Chem. Front., 2015, 2, 346 DOI: 10.1039/C4QO00324A

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