Issue 5, 2015
From the journal:

Inorganic Chemistry Frontiers

Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes†

Casey J. Stephenson,a   Joseph T. Hupp*a  and  Omar K. Farha*ab  

* Corresponding authors

a Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA
E-mail: j-hupp@northwestern.edu, o-farha@northwestern.edu

b Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

Abstract

Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

Graphical abstract: Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

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Article information

DOI
https://doi.org/10.1039/C5QI00010F
Article type
Research Article
Submitted
20 jan 2015
Accepted
18 feb 2015
First published
06 mar 2015

Inorg. Chem. Front., 2015,2, 448-452

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Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

C. J. Stephenson, J. T. Hupp and O. K. Farha, Inorg. Chem. Front., 2015, 2, 448 DOI: 10.1039/C5QI00010F

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