Issue 22, 2014
From the journal:

RSC Advances

Anion-dependent spin crossover in solution for an iron(ii) complex of a 1H-pyrazolyl ligand†

Simon A. Barretta  and  Malcolm A. Halcrow*a  

* Corresponding authors

a School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK
E-mail: m.a.halcrow@leeds.ac.uk
Fax: +44 (0)113 343 6565
Tel: +44 (0)113 343 6506

Abstract

The spin-crossover equilibrium midpoint temperature (T1/2) in [Fe(3-bpp)2]X2 (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) varies from 259 K when X− = BPh4− to 277 K when X− = Br−, at 10 mM concentrations in an acetone–water solvent mixture.

Graphical abstract: Anion-dependent spin crossover in solution for an iron(ii) complex of a 1H-pyrazolyl ligand

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Article information

DOI
https://doi.org/10.1039/C4RA00230J
Article type
Communication
Submitted
09 jan 2014
Accepted
11 feb 2014
First published
12 feb 2014

RSC Adv., 2014,4, 11240-11243

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Anion-dependent spin crossover in solution for an iron(II) complex of a 1H-pyrazolyl ligand

S. A. Barrett and M. A. Halcrow, RSC Adv., 2014, 4, 11240 DOI: 10.1039/C4RA00230J

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