Issue 8, 2014

N-heterocyclic carbene catalysed oxidative esterification of aliphatic aldehydes

Abstract

N-heterocyclic carbene-catalyzed oxidative esterification of various aliphatic aldehydes is reported. A commercially available bisquinone is used as an external oxidant and rubidium carbonate is best suited as base to run these processes. With the novel method various aliphatic esters are directly obtained in good to excellent yields from the corresponding aldehydes and alcohols.

Graphical abstract: N-heterocyclic carbene catalysed oxidative esterification of aliphatic aldehydes

Supplementary files

Article information

Article type
Research Article
Submitted
03 jun 2014
Accepted
21 jul 2014
First published
22 jul 2014

Org. Chem. Front., 2014,1, 936-939

Author version available

N-heterocyclic carbene catalysed oxidative esterification of aliphatic aldehydes

R. C. Samanta and A. Studer, Org. Chem. Front., 2014, 1, 936 DOI: 10.1039/C4QO00164H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements