Issue 4, 2014

Synthesis of organic halides via palladium(0) catalysis

Abstract

This critical review provides a brief overview of recent advances in the palladium(0)-catalysed synthesis of organic halides. It is well established that very sterically hindered phosphine ligands are capable of promoting the reductive elimination of carbon halides from C–Pd(II)–X species (X = F, Cl, Br, I), which has proved to be a more common process than was previously assumed and exhibits great potential for organic halides synthesis, including aryl fluorides.

Graphical abstract: Synthesis of organic halides via palladium(0) catalysis

Article information

Article type
Review Article
Submitted
06 jan 2014
Accepted
17 feb 2014
First published
14 mar 2014

Org. Chem. Front., 2014,1, 439-446

Author version available

Synthesis of organic halides via palladium(0) catalysis

C. Chen and X. Tong, Org. Chem. Front., 2014, 1, 439 DOI: 10.1039/C4QO00004H

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