Issue 20, 2012

The high yielding synthesis of pillar[5]arenes under Friedel–Crafts conditions explained by dynamic covalent bond formation

Abstract

Systematic investigations of the cyclooligomerization of 1,4-disubstituted hydroquinone derivatives under Friedel–Crafts conditions have been carried out to demonstrate that the formation of pillar[5]arenes occurs under thermodynamic control.

Graphical abstract: The high yielding synthesis of pillar[5]arenes under Friedel–Crafts conditions explained by dynamic covalent bond formation

  • This article is part of the themed collection: Aromaticity

Supplementary files

Article information

Article type
Communication
Submitted
02 nov 2011
Accepted
01 dec 2011
First published
02 dec 2011

Chem. Commun., 2012,48, 2576-2578

The high yielding synthesis of pillar[5]arenes under Friedel–Crafts conditions explained by dynamic covalent bond formation

M. Holler, N. Allenbach, J. Sonet and J. Nierengarten, Chem. Commun., 2012, 48, 2576 DOI: 10.1039/C2CC16795F

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