Issue 7, 2005

New reactions of β-diketiminatolanthanoid complexes: sterically induced self-deprotonation of β-diketiminato ligands

Abstract

Attempted synthesis of sterically demanding bis- or tris-β-diketiminato complexes of lanthanoids resulted in ligand deprotonation and the formation of complexes containing both a “normal” and a deprotonated ligand; one of these on protonation gave the first cationic β-diketiminato–Ln complex.

Graphical abstract: New reactions of β-diketiminatolanthanoid complexes: sterically induced self-deprotonation of β-diketiminato ligands

Supplementary files

Article information

Article type
Communication
Submitted
28 okt 2004
Accepted
26 nov 2004
First published
06 jan 2005

Chem. Commun., 2005, 951-953

New reactions of β-diketiminatolanthanoid complexes: sterically induced self-deprotonation of β-diketiminato ligands

P. B. Hitchcock, M. F. Lappert and A. V. Protchenko, Chem. Commun., 2005, 951 DOI: 10.1039/B416549G

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