Issue 58, 2016

Synthesis of aryl trimethylstannanes from aryl halides: an efficient photochemical method

Abstract

An efficient transition-metal-free photochemical method featuring excellent functional group tolerance, mild reaction conditions and short reaction times has been discovered and developed for the synthesis of (hetero)aryl trimethylstannanes from (hetero)aryl halides. A photo-initiated radical chain mechanism was proposed based on preliminary mechanistic studies.

Graphical abstract: Synthesis of aryl trimethylstannanes from aryl halides: an efficient photochemical method

Supplementary files

Article information

Article type
Communication
Submitted
04 feb 2016
Accepted
18 mar 2016
First published
18 mar 2016

Chem. Commun., 2016,52, 9125-9128

Synthesis of aryl trimethylstannanes from aryl halides: an efficient photochemical method

K. Chen, P. He, S. Zhang and P. Li, Chem. Commun., 2016, 52, 9125 DOI: 10.1039/C6CC01135G

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