Issue 58, 2016

Directly linked hydroporphyrin dimers

Abstract

Directly linked hydroporphyrin (chlorin) dimers were accessed regioselectively from bromochlorins. Versatile 15-borylated chlorins were prepared in excellent yield via Miyaura borylation. Suzuki coupling yielded mesomeso-linked homo- and heterodimers, and meso-β-linked dimers. The photophysical and electrochemical properties of the dimers are reported.

Graphical abstract: Directly linked hydroporphyrin dimers

Supplementary files

Article information

Article type
Communication
Submitted
18 jan 2016
Accepted
03 feb 2016
First published
03 feb 2016

Chem. Commun., 2016,52, 9056-9058

Author version available

Directly linked hydroporphyrin dimers

R. Xiong, A. I. Arkhypchuk, D. Kovacs, A. Orthaber and K. Eszter Borbas, Chem. Commun., 2016, 52, 9056 DOI: 10.1039/C6CC00516K

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