Trifluoromethyl-pyrrolo[2,1-a]isoquinolines, which are difficult to prepare via traditional methods, could be readily prepared via a tungsten-catalysed decarboxylative [3 + 2] cycloaddition aromatization process.
The metal-to-ligand stoichiometry and metal identity are of primary importance for the development of metal complexes of thiosemicarbazones as effective inhibitors of tubulin polymerization.
NI-FL demonstrates strong absorption in the visible light range, an elongated triplet excited state lifetime and enhanced performance in selective sulfide photooxidation through radical intermediates.
A Pt(II) tripyridine salt is reported, which is reversible to acetonitrile and irreversible to methanol, because of the different hydrogen bonding.
A non-labile bis(terpyridine)-CdII complex was designed, synthesized, and utilized for the construction of an array of metlloligands through multiple reactions, eventually leading to the successful quantitative self-assembly of a metallocatenane.