Insight into copper coordination in O2 reduction by water-soluble cytochrome c oxidase models

Mathilde Berthe, Corinne Boudon, Nolwenn Le Breton, Hiroaki Kitagishi, Koji Oohora, Takashi Hayashi, Jennifer A. Wytko and Jean Weiss

Dalton Trans., 2025, 54, 3659
DOI: 10.1039/D4DT03188A

Visible-light-driven copper(ii) catalysis for 2,3-disubstituted quinazolinone synthesis via Ullmann N-arylation and C–H oxidative amidation

Ahmed Th. Abdulghaffar, Pei Hu, Yifan Hu, Chenxu Liu, Yanrong Ren, Zhongyan Cao, Yuanqing Xu, Min Jiang and Hao Xu

Org. Biomol. Chem., 2025, 23, 3800
DOI: 10.1039/D5OB00063G

The development of cage phosphine ‘DalPhos’ ligands to enable nickel-catalyzed cross-couplings of (hetero)aryl electrophiles

Kathleen M. Morrison and Mark Stradiotto

Chem. Sci., 2024, 15, 7394
DOI: 10.1039/D4SC01253D

Photoredox/copper-catalyzed formal cyclopropanation of olefins

Li-Xin Li, Jie Zhao, Chen-Rui Li, Gaolei Sun, Xu Guo, Han-Wei Li, Baokun Qiao, Zhonghua Li, Kai Hu and Zhenqiang Zhang

Org. Chem. Front., 2024, 11, 1062
DOI: 10.1039/D3QO01739G

New reactivity of late 3d transition metal complexes in catalytic reactions of alkynes

Shenghan Teng, Peiyao Liang and Jianrong Steve Zhou

Chem. Soc. Rev., 2025, 54, 2664
DOI: 10.1039/D4CS01130A

Copper-Catalyzed Annulation of α,β-Unsaturated Ketoximes with Dialkyl Acetylenedicarboxylates for the Synthesis of Highly Substituted Pyridines

Shi-Mei He, Yun-Bo Yang, Lv-Yan Liu, Ning Yu, Yu-Qiang Zhou, Jia-Hao Zhou, Mei-Jun Zheng, Xiao-Kun Jin, Kun Jiang and Ye Wei

Org. Lett., 2025, 27, 1100
DOI: 10.1021/acs.orglett.4c04351

A nickel metalloradical bearing a phenalenyl-based tridentate ligand

Hikaru Noguchi, Takuya Kodama, Soichi Kikkawa, Seiji Yamazoe and Mamoru Tobisu

Chemistry Letters, 2024, 53
DOI: 10.1093/chemle/upae236

Soft Copper Nanoimprinting via Solid-State Electrochemical Etching for Flexible Optoelectronics

Atsuki Tsuji, Taizo Kobayashi and Junji Murata

ACS Appl. Mater. Interfaces, 2025, 17, 21929
DOI: 10.1021/acsami.4c20732

Intercepting Ketone α-Arylation Intermediates in the DalPhos/Ni-Catalyzed Synthesis of Decorated Benzofurans and NH-Indoles

Joshua W. M. MacMillan, Katherine N. Robertson and Mark Stradiotto

ACS Catal., 2025, 15, 3751
DOI: 10.1021/acscatal.5c00428

Discovery of Ni(I) Complexes for CO2 Insertion Enabled by a Machine Learning-Computational-Selection Sequence

Julian A. Hueffel, Mathilde Rigoulet, Sebastian Wellig, Theresa Sperger, Jas S. Ward, Kari Rissanen and Franziska Schoenebeck

J. Am. Chem. Soc., 2025, 147, 26149
DOI: 10.1021/jacs.5c00441

Mechanisms of Photoredox Catalysis Featuring Nickel–Bipyridine Complexes

David A. Cagan, Daniel Bím, Nathanael P. Kazmierczak and Ryan G. Hadt

ACS Catal., 2024, 14, 9055
DOI: 10.1021/acscatal.4c02036

Rate Equations for Reversible Disproportionation Reactions and Fitting to Time-Course Data

James B. Gerken, Alexios Stamoulis, Madeline L. MacDonnell and Shannon S. Stahl

J. Phys. Chem. A, 2024, 128, 328
DOI: 10.1021/acs.jpca.3c05232

Revealing the complexation of 3-N,N-dimethylaminodithiocarbamoyl-1-propanesulfonic acid (DPS) with cuprous ion and its contribution to Cu electrodeposition

Jiseok Lee, Jihyun Kim, Sung Ki Cho and Jae Jeong Kim

Electrochimica Acta, 2025, 509, 145288
DOI: 10.1016/j.electacta.2024.145288

Electrochemical Nickel-Catalyzed C(sp2)-H Functionalization of Tropones with Aldehydes

Andrea Brunetti, Sofia Kiriakidi, Mauro Garbini, Giulia Monda, Chiara Zanardi, Carlos Silva López, Giulio Bertuzzi and Marco Bandini

ACS Catal., 2025, 15, 3184
DOI: 10.1021/acscatal.4c07120

Dynamic stereomutation of vinylcyclopropanes with metalloradicals

Marvin Mendel, Teresa M. Karl, Jegor Hamm, Sherif J. Kaldas, Theresa Sperger, Bhaskar Mondal and Franziska Schoenebeck

Nature, 2024, 631, 80
DOI: 10.1038/s41586-024-07555-1

Water and Air Stable Copper(I) Complexes of Tetracationic Catenane Ligands for Oxidative C−C Cross‐Coupling

Man Pang Tang, Lihui Zhu, Yulin Deng, Yi‐Xiang Shi, Samuel Kin‐Man Lai, Xiaoyong Mo, Xin‐Yu Pang, Chunyu Liu, Wei Jiang, Edmund Chun Ming Tse and Ho Yu Au‐Yeung

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202405971

Mechanistic Insights on the Challenging Trifluoromethylation of Ni(II)

Mathilde Rigoulet, Sebastian Wellig and Franziska Schoenebeck

ACS Catal., 2024, 14, 7456
DOI: 10.1021/acscatal.4c00907

Cu-Catalyzed Coupling of Aryl Halides Utilizing Ammonia and Hydroxypicolinamide Ligands

David J. Bernhardson, Ian Hotham, Liam S. Sharninghausen, Robert A. Singer and Daniel W. Widlicka

Org. Process Res. Dev., 2025, 29, 1554
DOI: 10.1021/acs.oprd.5c00101

Deposition of Tin Catalysts from Thiolated Precursor Organic Solutions for CO2 Reduction to Formate: A Potential‐Dependent Mechanism Study

Yaron S. Cohen, Sumesh Sadhujan, Sonal Rajput, Yakov Shitrit and Olga Iliashevsky

ChemPlusChem, 2025
DOI: 10.1002/cplu.202500208

Bis(benzimidazolin-2-ylidenes): Exploring the Impact of Ligand Properties in the Nickel-Catalyzed Suzuki–Miyaura Coupling

Claudia S. Zhang, Shreyas Rajesh, Abigail L. Moffett, Timothy H. Chen, Colin D. McMillen and Kerry-Ann Green

Organometallics, 2024, 43, 1988
DOI: 10.1021/acs.organomet.4c00138

Ar–X Coupling Reactions of Cationic Aryl Copper(II) Complexes with Organic Substrates: What Role Do Radicals Play?

Weam A. O. Altalhi, Jack G. Li, Allan J. Canty, Paul S. Donnelly, Jonathan M. White and Richard A. J. O'Hair

Chemistry A European J, 2025
DOI: 10.1002/chem.202500431

Cationic nickel(II) complexes bearing a phenalenyl-based tridentate ligand

Takuya Kodama, Hikaru Noguchi, Hayato Tsurugi and Mamoru Tobisu

Chemistry Letters, 2025, 54
DOI: 10.1093/chemle/upae251

Light Activation and Photophysics of a Structurally Constrained Nickel(II)–Bipyridine Aryl Halide Complex

Daniel Bím, Kaitlin M. Luedecke, David A. Cagan and Ryan G. Hadt

Inorg. Chem., 2024, 63, 4120
DOI: 10.1021/acs.inorgchem.3c03822

Roadmap to the Synthesis of Nickel Bisoxazoline Aryl Halide Complexes

Brennan D. McManus, Olivia R. Taylor, Nathan J. Coddington, Phillip Farias, Veronica Carta and Ana Bahamonde

Organometallics, 2025, 44, 1186
DOI: 10.1021/acs.organomet.5c00089

Selective Open-Shell Nickel Catalysis Driven by Redox-Transmetalation

Yu Gan, Xuejiao Li, Jun-Feng Zhou and Baihua Ye

Synlett, 2025, 36, 1609
DOI: 10.1055/a-2589-5014

Electrocatalytic Formal C(sp2)−H Alkylations via Nickel‐Catalyzed Cross‐Electrophile Coupling with Versatile Arylsulfonium Salts

Takuya Michiyuki, Simon L. Homölle, Neeraj K. Pandit and Lutz Ackermann

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202401198

Late-Stage C(sp2)–C(sp3) Diversification via Nickel Oxidative Addition Complexes

Carlota Odena, Tomás G. Santiago, María Lourdes Linares, Nahury Castellanos-Blanco, Ryan T. McGuire, Belén Chaves-Arquero, Jose Manuel Alonso, Alejandro Diéguez-Vázquez, Eric Tan, Jesús Alcázar, Peter Buijnsters, Santiago Cañellas and Ruben Martin

J. Am. Chem. Soc., 2024, 146, 21264
DOI: 10.1021/jacs.4c08404

Rapid Methylation of Aryl Bromides Using Air‐Stable DABCO‐Bis(Trimethylaluminum) via Nickel Metallaphotoredox Catalysis

Jonas Djossou, Andrea Aloia, Luca Capaldo, Demi D. Snabilié, Morgan Regnier, Jasper H.A. Schuurmans, Antonio Monopoli, Bas de Bruin and Timothy Noël

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202508710

Alkyl Cyclopropyl Ketones in Catalytic Formal [3 + 2] Cycloadditions: The Role of SmI2 Catalyst Stabilization

Jack I. Mansell, Song Yu, Muze Li, Emma Pye, Chaofan Yin, Frédéric Beltran, James A. Rossi-Ashton, Ciro Romano, Nikolas Kaltsoyannis and David J. Procter

J. Am. Chem. Soc., 2024, 146, 12799
DOI: 10.1021/jacs.4c03073

Aerobic Oxysulfonylation of Olefins Using N-Sulfonylaminophthalimides as Sulfonyl Radical Precursors

Zhenxing Yan, Jie Ye, Heng Wang, Tao Chen, Ze-Feng Xu, Mingming Yu and Chuan-Ying Li

Org. Lett., 2024, 26, 6647
DOI: 10.1021/acs.orglett.4c02303

Synthesis of allenones via nickel-catalyzed reductive coupling of propargyl esters with acyl chlorides

Zhen Song, Yueming Wang, Ming Ma and Yuanhong Ma

Tetrahedron Chem, 2024, 12, 100113
DOI: 10.1016/j.tchem.2024.100113

Water and Air Stable Copper(I) Complexes of Tetracationic Catenane Ligands for Oxidative C−C Cross‐Coupling

Man Pang Tang, Lihui Zhu, Yulin Deng, Yi‐Xiang Shi, Samuel Kin‐Man Lai, Xiaoyong Mo, Xin‐Yu Pang, Chunyu Liu, Wei Jiang, Edmund Chun Ming Tse and Ho Yu Au‐Yeung

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202405971

Nickel catalyzed C-N coupling of haloarenes with B2N4 reagents

Qianqian Chang, Qini Li, Yi-Hui Deng, Tian-Yu Sun, Yun-Dong Wu and Leifeng Wang

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-58438-6

Advances in Copper and Nickel C─N and C─O Cross‐Couplings of (Hetero)Aryl Chlorides Enabled by Ancillary Ligand Development

Kathleen M. Morrison and Mark Stradiotto

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202501858

An Organocopper(III) Fluoride Triggering C−CF3 Bond Formation

Daniel Joven‐Sancho, Andrea Echeverri, Nathalie Saffon‐Merceron, Julia Contreras‐García and Noel Nebra

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202319412

Overcoming Electron Bias in Hydroarylation of Phenylpropiolic Acid Derivatives To Enable Highly Reversed Regio- and Stereoselectivity via Steric and Transient Post Addition Coordination

Hui Li, Xu Tian, Qin-Qin Dang, Jing Zhang and Zhen-Kang Wen

ACS Catal., 2024, 14, 9985
DOI: 10.1021/acscatal.4c01944

Nickel-Catalyzed Asymmetric Homobenzylic Hydroamidation of Aryl Alkenes to Access Chiral β-Arylamides

Xiang Lyu, Eojin Jeon, Changhyeon Seo, Dongwook Kim and Sukbok Chang

J. Am. Chem. Soc., 2025, 147, 8928
DOI: 10.1021/jacs.5c00867

Advances in understanding comproportionation and disproportionation in nickel catalysis

Craig S. Day

Pure and Applied Chemistry, 2024, 96, 437
DOI: 10.1515/pac-2024-0106

Unraveling a Complex Mechanistic Picture of Photochemical Nickel-Catalyzed THF Arylation through Product Enantioselectivity Analysis

Lang C. Hung, Brennan D. McManus, Olivia R. Taylor and Ana Bahamonde

Synlett, 2025, 36, 1469
DOI: 10.1055/s-0043-1775479

On the Existence and Relevance of Copper(III) Fluorides in Oxidative Trifluoromethylation

Daniel Joven-Sancho and Noel Nebra

Synlett, 2025, 36, 289
DOI: 10.1055/a-2351-5090

Ni-catalysed remote C(sp3)–H functionalization using chain-walking strategies

Ciro Romano and Ruben Martin

Nat Rev Chem, 2024, 8, 833
DOI: 10.1038/s41570-024-00649-4

Formal 1,1-Hydrocyanation Reaction of Alkynyl Halides with Isocyanides Enabled by Dual Nickel/Base Catalysis Relay

Bingwei Zhou, Zhengzhe Huang, Zhao Gao and Yuanyuan Hu

Org. Lett., 2024, 26, 10511
DOI: 10.1021/acs.orglett.4c03901

Nickel-Catalyzed Photoredox Allenylation of Alkyl Halides

Tingjun Hu, Camille Beluze, Vincent Fagué, Oho Eliantine Kambire, Didier Bouyssi, Nuno Monteiro and Abderrahmane Amgoune

Org. Lett., 2024, 26, 9519
DOI: 10.1021/acs.orglett.4c03512

Synthesis and characterization of alkali metal salts bearing a phenalenyl-based tridentate ligand

Takuya Kodama, Hikaru Noguchi, Hayato Tsurugi and Mamoru Tobisu

Chemistry Letters, 2025, 54
DOI: 10.1093/chemle/upae246

Rapid Methylation of Aryl Bromides Using Air‐Stable DABCO‐Bis(Trimethylaluminum) via Nickel Metallaphotoredox Catalysis

Jonas Djossou, Andrea Aloia, Luca Capaldo, Demi D. Snabilié, Morgan Regnier, Jasper H.A. Schuurmans, Antonio Monopoli, Bas de Bruin and Timothy Noël

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202508710

Bulk depolymerization of PMMA using difunctional pyromellitic or monofunctional phthalimidic ATRP initiators

Ferdinando De Luca Bossa, Gorkem Yilmaz, Carlo Gericke and Krzysztof Matyjaszewski

European Polymer Journal, 2025, 223, 113646
DOI: 10.1016/j.eurpolymj.2024.113646

An Organocopper(III) Fluoride Triggering C−CF3 Bond Formation

Daniel Joven‐Sancho, Andrea Echeverri, Nathalie Saffon‐Merceron, Julia Contreras‐García and Noel Nebra

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202319412

Elektrokatalytische formale C(sp2)−H Alkylierung via Nickel‐katalysierter elektrophiler Kreuzkupplung mit vielseitigen Arylsulfoniumsalzen

Takuya Michiyuki, Simon L. Homölle, Neeraj K. Pandit and Lutz Ackermann

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202401198

Possibility of Nickel(I) complex in Suzuki-Miyaura coupling using pincer-type 1,2,3-triazolylidene Nickel(II) complex

Kanta Tomomatsu, Yuji Yamada, Yuji Koga and Kouki Matsubara

Bulletin of the Chemical Society of Japan, 2024, 97
DOI: 10.1093/bulcsj/uoad015