Borane-catalyzed arylation of aryldiazoacetates withN,N-dialkylanilines

Cheng-Yu Chen, Jing-Hao Zhao, Li-Xue Xiong, Feiyi Wang, Guichun Yang and Chao Ma

Org. Biomol. Chem., 2022, 20, 4101
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BF3·OEt2 catalyzed chemoselective CC bond cleavage of α,β-enones: an unexpected synthesis of 3-alkylated oxindoles and spiro-indolooxiranes

Sengodagounder Muthusamy and Ammasi Prabu

Org. Biomol. Chem., 2022, 20, 558
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1,1,2-Trifunctionalization of terminal alkynes by imine/borane frustrated Lewis pairs

Aziz Ullah and Guo-Qiang Chen

Org. Chem. Front., 2022, 9, 4421
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Borane catalyzed transesterification of tert-butyl esters using α-aryl α-diazoesters

Maying Yan, Lei Xiao, Jiangkun Xiong, Lvnan Jin, Douglas W. Stephan and Jing Guo

Org. Biomol. Chem., 2023, 21, 8279
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Aryl boronic acid-controlled divergent ring-contraction and ring-opening/isomerization reaction of tert-cyclobutanols enabled by nickel catalysis

Zhichang He, Zhengwen Wang, Zhao Gao, Hongwei Qian, Wangqiannan Ding, Hongwei Jin, Yunkui Liu and Bingwei Zhou

Org. Biomol. Chem., 2023, 21, 6493
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B(C6F5)3-catalyzed Wolff rearrangement/[2 + 2] and [4 + 2] cascade cyclization of α-diazoketones with imines

Weihong Song, Jing Guo and Douglas W. Stephan

Org. Chem. Front., 2023, 10, 1754
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B(C6F5)3-catalyzed cyclopropanation of 3-alkenyl-oxindoles with diazomethanes

Lei Xiao, Lvnan Jin, Yunbo Zhao, Jing Guo and Douglas W. Stephan

Chem. Commun., 2023, 59, 1833
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B(C6F5)3-Catalyzed Diastereoselective and Divergent Reactions of Vinyldiazo Esters with Nitrones: Synthesis of Highly Functionalized Diazo Compounds

Katarina Stefkova, Michael G. Guerzoni, Yara van Ingen, Emma Richards and Rebecca L. Melen

Org. Lett., 2023, 25, 500
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Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters

Kexin Dong, Xun-Shen Liu, Xiaoyan Wei, Yuting Zhao and Lu Liu

Green Synthesis and Catalysis, 2021, 2, 385
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Acid‐Catalyzed Carbene Transfer from Diazo Compounds: Carbocation versus Carbene as Key Intermediate

Zheng‐Wang Qu, Hui Zhu and Stefan Grimme

Eur J Org Chem, 2022, 2022
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DigiChemTree enables programmable light-induced carbene generation for on demand chemical synthesis

Abhilash Rana, Ruchi Chauhan, Amirreza Mottafegh, Dong Pyo Kim and Ajay K. Singh

Commun Chem, 2024, 7
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Frustrated Lewis pairs reactivity across the periodic table: The 2024 Catalysis Award Lecture

Douglas W. Stephan

Can. J. Chem., 2025
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Tris(pentafluorophenyl)borane‐Catalyzed Carbenium Ion Generation and Autocatalytic Pyrazole Synthesis—A Computational and Experimental Study

Ayan Dasgupta, Rasool Babaahmadi, Sanjukta Pahar, Katarina Stefkova, Lukas Gierlichs, Brian F. Yates, Alireza Ariafard and Rebecca L. Melen

Angew Chem Int Ed, 2021, 60, 24395
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Understanding the Influence of Donor‐Acceptor Diazo Compounds on the Catalyst Efficiency of B(C6F5)3 Towards Carbene Formation

Rasool Babaahmadi, Ayan Dasgupta, Christopher J. T. Hyland, Brian F. Yates, Rebecca L. Melen and Alireza Ariafard

Chemistry A European J, 2022, 28
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Comparison of the Efficiency of B–O and B–C Bond Formation Pathways in Borane-Catalyzed Carbene Transfer Reactions Using α-Diazocarbonyl Precursors: A Combined Density Functional Theory and Machine Learning Study

Kaveh Farshadfar and Kari Laasonen

ACS Catal., 2024, 14, 14486
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Reactions of Frustrated Lewis Pairs with Chloro‐Diazirines: Cleavage of N=N Double Bonds

Dipendu Mandal, Ting Chen, Zheng‐Wang Qu, Stefan Grimme and Douglas W. Stephan

Angewandte Chemie, 2022, 134
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Borane Catalyzed Selective Diazo Cross‐Coupling Towards Pyrazoles

Ayan Dasgupta, Sanjukta Pahar, Rasool Babaahmadi, Lukas Gierlichs, Brian F. Yates, Alireza Ariafard and Rebecca L. Melen

Adv Synth Catal, 2022, 364, 773
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Activation of Diazo Compounds by Fluorinated Triarylborane Catalysts

Milan Pramanik and Rebecca L. Melen

Synthesis, 2023, 55, 3906
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Tris(pentafluorphenyl)boran‐katalysierte Erzeugung von Carbenium‐Ionen und autokatalytische Pyrazol‐Synthese – eine theoretische und experimentelle Studie

Ayan Dasgupta, Rasool Babaahmadi, Sanjukta Pahar, Katarina Stefkova, Lukas Gierlichs, Brian F. Yates, Alireza Ariafard and Rebecca L. Melen

Angewandte Chemie, 2021, 133, 24599
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Triarylborane Catalyzed Carbene Transfer Reactions Using Diazo Precursors

Ayan Dasgupta, Emma Richards and Rebecca L. Melen

ACS Catal., 2022, 12, 442
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Reactions of Frustrated Lewis Pairs with Chloro‐Diazirines: Cleavage of N=N Double Bonds

Dipendu Mandal, Ting Chen, Zheng‐Wang Qu, Stefan Grimme and Douglas W. Stephan

Angew Chem Int Ed, 2022, 61
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Tris(pentafluorophenyl)borane‐Catalyzed Oxygen Insertion Reaction of α‐Diazoesters (α‐Diazoamides) with Dimethyl Sulfoxide

Xiao‐Yang Wu, Wen‐Xia Gao, Yun‐Bing Zhou, Miao‐Chang Liu and Hua‐Yue Wu

Adv Synth Catal, 2022, 364, 750
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