High temperature spin crossover behaviour of mononuclear bis-(thiocyanato)iron(ii) complexes with judiciously designed bidentate N-donor Schiff bases with varying substituents

Kishalay Bhar, Wenbin Guo, Mathieu Gonidec, Venkata Nikhil Raj M, Surabhi Bhatt, Franc Perdih, Philippe Guionneau, Guillaume Chastanet and Anuj K. Sharma

Dalton Trans., 2022, 51, 9302
DOI: 10.1039/D2DT00416J

Halogen bond-enhanced spin dynamics: investigating co-crystallization effects on spin crossover in mononuclear Mn(iii) Schiff-base complexes

Sheng-Ze Zhao, Li-Wen Chen, Hai Zhu, Hao-Zhe Zhang, Chang Liu, Chun-Yan Qin, Hai-Ying Wang, Yong-Hua Li and Shi Wang

Dalton Trans., 2025, 54, 9405
DOI: 10.1039/D5DT00841G

Rotational order–disorder and spin crossover behaviour in a neutral iron(ii) complex based on asymmetrically substituted large planar ionogenic ligand

Maksym Seredyuk, Kateryna Znovjyak, Francisco Javier Valverde-Muñoz, M. Carmen Muñoz, Igor O. Fritsky and José Antonio Real

Dalton Trans., 2024, 53, 8041
DOI: 10.1039/D4DT00368C

60 K wide hysteresis embracing room temperature in a fluorescent FeII spin transition complex

Maksym Seredyuk, Kateryna Znovjyak, Francisco Javier Valverde-Muñoz, M. Carmen Muñoz, Teresa Delgado, Ivan da Silva and José Antonio Real

Inorg. Chem. Front., 2025, 12, 4583
DOI: 10.1039/D5QI00856E

Unprecedented direct spatiotemporal imaging of a reversible interface propagation in a switchable cooperative Fe(iii) spin crossover material

Marcos A. Bento, Nour el islam Belmouri, André Fernandes, David Ndrio, Guillaume Bouchez, Longhe Li, Liliana P. Ferreira, Hermínio P. Diogo, João Rocha, Francesc Viñes, Adrià Gil, Kamel Boukheddaden and Paulo N. Martinho

Inorg. Chem. Front., 2026, 13, 1660
DOI: 10.1039/D5QI01876E

Spin crossover molecular ceramics by Cool-SPS: consequences on switching features beyond microstructural effects

Liza El-Khoury, Nathalie Daro, Guillaume Chastanet, Patrick Rosa, Dominique Denux, Laetitia Etienne, Vincent Mazel, Michael Josse and Mathieu Marchivie

Mater. Adv., 2024, 5, 1502
DOI: 10.1039/D3MA00688C

Co-crystallisation as a modular approach to the discovery of spin-crossover materials

Lee T. Birchall, Giada Truccolo, Lewis Jackson and Helena J. Shepherd

Chem. Sci., 2022, 13, 3176
DOI: 10.1039/D1SC04956A

Switching on thermal and light-induced spin crossover by desolvation of [Fe(3-bpp)2](XO4)2·solvent (X = Cl, Re) compounds

Abdelhak Djemel, Olaf Stefanczyk, Cédric Desplanches, Kunal Kumar, Rachid Delimi, Farouk Benaceur, Shin-ichi Ohkoshi and Guillaume Chastanet

Inorg. Chem. Front., 2021, 8, 3210
DOI: 10.1039/D1QI00446H

The role of intermolecular interactions in [Fe(X-salEen)2]ClO4 spin crossover complexes

Marcos A. Bento, Tiago Gomes, Frederico F. Martins, Adrià Gil, Liliana P. Ferreira, Sónia Barroso, Clara S. B. Gomes, Yann Garcia and Paulo N. Martinho

Dalton Trans., 2024, 53, 8791
DOI: 10.1039/D4DT00400K

Aliphatic Chains and External Pressure as Tools for Fine-Tuning Spin Transition Temperature and Cooperativity

Hanlin Yu, Maksym Seredyuk, Kateryna Znovjyak, Nikita Liedienov, Wei Xu, Francisco Javier Valverde-Muñoz, M. Carmen Muñoz, Joachim Kusz, Maria Książek, Ruixin Li, Quanjun Li, Bingbing Liu, Gábor Molnár, Georgiy Levchenko and José Antonio Real

Inorg. Chem., 2025, 64, 23399
DOI: 10.1021/acs.inorgchem.5c03403

A new square pyramidal copper(II) complex [Cu(C10H24N4)Br]Br: Crystal structure, thermal analysis, Hirschfeld surfaces, electrical and semiconducting properties

Wassim Maalej, Philippe Guionneau and Zakaria Elaoud

Journal of Molecular Structure, 2021, 1241, 130630
DOI: 10.1016/j.molstruc.2021.130630

Deciphering the Unusual Pressure-Induced Electron Transfer in the Molecular Switch {[Fe(Tp)(CN)3]2[Co(vbik)2]2}·(BF4)2·2MeOH

Buqin Xu, Yanling Li, Benoît Baptiste, Lise-Marie Chamoreau, Damian Paliwoda, Shiteng Mi, Gábor Molnár, Kamel Boukheddaden and Rodrigue Lescouëzec

Chem. Mater., 2024
DOI: 10.1021/acs.chemmater.4c02347

Halogen-Driven Spin Dynamics: Exploring Correlation of Cooperativity and Spin Crossover in Solid-State Mononuclear Fe(III) Schiff-Base Complexes

Li-Wen Chen, Hai Zhu, Hua-Wei Zhou, Hao-Zhe Zhang, Sheng-Ze Zhao, Yong-Hua Li and Shi Wang

Inorg. Chem., 2025, 64, 7203
DOI: 10.1021/acs.inorgchem.5c00885

Coupling and decoupling of spin crossover and ferroelastic distortion: Unsymmetric hysteresis loop, phase diagram, and sequence of phases

Eric Collet and Giovanni Azzolina

Phys. Rev. Materials, 2021, 5
DOI: 10.1103/PhysRevMaterials.5.044401

Supramolecular architectures of mononuclear nickel(II) and homobinuclear copper(II) complexes with the 5,5′-dimethyl-2,2′-bipyridine ligand: Syntheses, crystal structures and Hirshfeld surface analyses

Wassim Maalej, Rim Jaballi, Asma Ben Rached, Philippe Guionneau, Nathalie Daro and Zakaria Elaoud

Journal of Molecular Structure, 2022, 1250, 131728
DOI: 10.1016/j.molstruc.2021.131728

Role of harmonic and anharmonic interactions in controlling the cooperativity of spin-crossover molecular crystals

Oleksandr Markin, Iurii Gudyma and Kamel Boukheddaden

Phys. Rev. B, 2024, 110
DOI: 10.1103/PhysRevB.110.174416

Substituent effect on the spin transition of Mixed-Valence Cyanide-Bridged {FeIII2FeII} complexes

Jie Huang, Yan-Rui Lei, Yu-Jing Gao, Pan-Dong Mao, Yin-Shan Meng and Tao Liu

Inorganic Chemistry Communications, 2024, 159, 111789
DOI: 10.1016/j.inoche.2023.111789

Reversible Colossal Barocaloric Effect of a New FeII Molecular Complex with Low Hysteretic Spin Crossover Behavior

Maksym Seredyuk, Ruixin Li, Kateryna Znovjyak, Zhe Zhang, Francisco Javier Valverde‐Muñoz, Bing Li, M. Carmen Muñoz, Quanjin Li, Bingbing Liu, Georgiy Levchenko and José Antonio Real

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202315487

Advances in spin crossover metal complexes: a comprehensive review on its gas sensing applications

Farva Fiaz, Amna Siddique, Muhammad Fazle Rabbee, Muhammad Bin Hanif, Saad M. Al-Baqami, Shehzada Muhammad Sajid Jillani, Naif S. Almuqati, Md. Rezaur Rahman, Mohammad Asaduzzaman Chowdhury, Muhammad Nadeem Akhtar, Mohammad Mizanur Rahman Khan, Mohammed M. Rahman and Tahir Ali Sheikh

Reviews in Inorganic Chemistry, 2026, 46, 35
DOI: 10.1515/revic-2024-0108

Design of Photomagnetic Ultra‐Thin Films by Electrodeposition of Switchable Cyanide‐Bridged Fe4Co4 Complexes

Amina Benchohra, Jessem Landoulsi, Niéli Daffé, Christophe Méthivier, Emmanuel Maisonhaute, Laure Fillaud, Jan Dreiser, Michal Studniarek, Marie‐Anne Arrio, Yanling Li, Sofia Frida Russi, David Kreher and Rodrigue Lescouëzec

Small, 2025, 21
DOI: 10.1002/smll.202408917

Investigation on X-ray diffraction, IR, UV-visible, fluorescence, thermogravimetric, DFT studies, and molecular docking approach of a new C6H17.16Cl3CuN3O0.58 complex

Wijdene Nbili, Musa Runde, Rawlings A. Timothy, Frédéric Lefebvre, Werner Kamisky, Chérif Ben Nasr and Kamel Kaabi

Journal of Molecular Structure, 2025, 1326, 141049
DOI: 10.1016/j.molstruc.2024.141049

Polymer Mediated Control and Migration Effects in Spin-Crossover-Polymer Hybrids Towards Tunable Thermal Sensing Applications

Georgios N. Mathioudakis, Georgios Kaldiris, Solveig Felton, Grace Genevieve Morgan, George A. Voyiatzis and Zoi G. Lada

Polymers, 2025, 17, 3226
DOI: 10.3390/polym17233226

Order–Disorder, Symmetry Breaking, and Crystallographic Phase Transition in a Series of Bis(trans-thiocyanate)iron(II) Spin Crossover Complexes Based on Tetradentate Ligands Containing 1,2,3-Triazoles

Maksym Seredyuk, Kateryna Znovjyak, Francisco Javier Valverde-Muñoz, M. Carmen Muñoz, Volodymyr M. Amirkhanov, Igor O. Fritsky and José Antonio Real

Inorg. Chem., 2023, 62, 9044
DOI: 10.1021/acs.inorgchem.3c00830

Photo‐Thermal Switching of Individual Plasmonically Activated Spin Crossover Nanoparticle Imaged by Ultrafast Transmission Electron Microscopy

Yaowei Hu, Matthieu Picher, Ngoc Minh Tran, Marlène Palluel, Laurentiu Stoleriu, Nathalie Daro, Stephane Mornet, Cristian Enachescu, Eric Freysz, Florian Banhart and Guillaume Chastanet

Advanced Materials, 2021, 33
DOI: 10.1002/adma.202105586

Coupled spin cross-over and ferroelasticity: revisiting the prototype [Fe(ptz) 6 ](BF 4 ) 2 material

Eric Collet, Giovanni Azzolina, Jelena Jeftić and Marie-Hélène Lemée-Cailleau

Advances in Physics: X, 2023, 8
DOI: 10.1080/23746149.2022.2161936

Hierarchical Spin‐Crossover Cooperativity in Hybrid 1D Chains of FeII‐1,2,4‐Triazole Trimers Linked by [Au(CN)2]− Bridges

Lida Ezzedinloo, Katrina A. Zenere, Zixi Xie, Manan Ahmed, SynØve Scottwell, Mohan Bhadbhade, Helen E. A. Brand, Jack K. Clegg, Carol Hua, Natasha F. Sciortino, Lachlan C. Parker, Benjamin J. Powell, Cameron J. Kepert and Suzanne M. Neville

Chemistry A European J, 2021, 27, 5136
DOI: 10.1002/chem.202100358

Regulation of Multistep Spin Crossover Across Multiple Stimuli in a 2-D Framework Material

Manan Ahmed, Katrina A. Zenere, Natasha F. Sciortino, Kasun S. A. Arachchige, Gemma F. Turner, Jace Cruddas, Carol Hua, Jason R. Price, Jack K. Clegg, Francisco Javier Valverde-Muñoz, Jose A. Real, Guillaume Chastanet, Stephen A. Moggach, Cameron J. Kepert, Benjamin J. Powell and Suzanne M. Neville

Inorg. Chem., 2022, 61, 6641
DOI: 10.1021/acs.inorgchem.2c00530

Understanding of cooperative effects in molecule-based spin transition materials

Yan Fang, Yin-Shan Meng, Hiroki Oshio and Tao Liu

Coordination Chemistry Reviews, 2024, 500, 215483
DOI: 10.1016/j.ccr.2023.215483

The Investigation of Spin-Crossover Systems by Raman Spectroscopy: A Review

Zoi G. Lada

Magnetochemistry, 2022, 8, 108
DOI: 10.3390/magnetochemistry8090108

Exploring how interactions between components determine the cooperativity and magnetic properties of mononuclear Mn(III) spin crossover complexes

Li-Wen Chen, Li-Jing Wen, Hai Zhu, Hao-Zhe Zhang, Hai-Ying Wang, Chun-Yan Qin, Yong-Hua Li and Shi Wang

Journal of Molecular Structure, 2026, 1351, 144382
DOI: 10.1016/j.molstruc.2025.144382

Spin‐State Modulation in FeII‐Based Hofmann‐Type Coordination Polymers: From Molecules to Materials

Bhart Kumar, Abhik Paul, Dibya Jyoti Mondal, Piyush Paliwal and Sanjit Konar

The Chemical Record, 2022, 22
DOI: 10.1002/tcr.202200135

Supramolecular Tuning of Spin Crossover Properties in Isostructural Cocrystal Solvates

Lee T. Birchall, Amber T. Raja, Lewis Jackson and Helena J. Shepherd

Crystal Growth & Design, 2023, 23, 1768
DOI: 10.1021/acs.cgd.2c01282

105 K Wide Room Temperature Spin Transition Memory Due to a Supramolecular Latch Mechanism

Maksym Seredyuk, Kateryna Znovjyak, Francisco Javier Valverde-Muñoz, Ivan da Silva, M. Carmen Muñoz, Yurii S. Moroz and José Antonio Real

J. Am. Chem. Soc., 2022, 144, 14297
DOI: 10.1021/jacs.2c05417

Mean-field theory of spin-crossover transition in elastic molecular crystals with Morse potential energy

Oleksandr Markin and Iurii Gudyma

Molecular Crystals and Liquid Crystals, 2024, 768, 50
DOI: 10.1080/15421406.2024.2330161

Co‐crystallization as a Strategy for Tuning Spin Crossover Properties of Mononuclear Mn(III) Schiff‐base Complexes

Li‐Wen Chen, Hao‐Zhe Zhang, Sheng‐Ze Zhao, Hua‐Wei Zhou, Yong‐Hua Li, Chao Tang and Shi Wang

Eur J Inorg Chem, 2024, 27
DOI: 10.1002/ejic.202400432

Behavior of Occupied and Void Space in Molecular Crystal Structures at High Pressure

Cameron J. G. Wilson, Tomas Cervenka, Peter A. Wood and Simon Parsons

Crystal Growth & Design, 2022, 22, 2328
DOI: 10.1021/acs.cgd.1c01427