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Abstract | Cited by

Photolysis of 1,3,2,4-benzodithiadiazine and its derivatives in hydrocarbon solutions yields dinitrogen and stable 1,2,3-benzodithiazolyls (Herz radicals) whose interaction with dioxygen leads finally to O[double bond, length as m-dash]S[double bond, length as m-dash]N-substituted diphenyl disulfides via a self termination-like process with an effective second-order rate constant depending linearly on the concentration of dissolved O2.

Graphical abstract: Photochemistry of 1,3,2,4-benzodithiadiazines: formation and oxidation of 1,2,3-benzodithiazolyl radicals

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