Catalytic asymmetric transformation of platform chemicals derived from lignocellulosic biomass

Abstract

The chemical industry still relies heavily on fossil fuels as carbon-based building blocks. However, the finite nature of this resource is driving a shift toward sustainable alternatives, such as lignocellulosic biomass. This review summarizes recent progress (from 2015 to 2025) in the catalytic asymmetric transformation of key platform chemicals derived from lignocellulosic biomass, including 5-hydroxymethylfurfural, 5-(chloromethyl)furfural, and levulinic acid. It also discusses the underlying reaction mechanisms and product derivatization, providing insights to support future advancements in sustainable chemistry.