Issue 26, 2022
From the journal:

RSC Advances

N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols†

Tatsuki Nagata,a   Kanji Okada,a   Ryota Kondo,a   Takashi Toyao, ORCID logo b   Ken-ichi Shimizu, ORCID logo b   Takeyuki Suzuki ORCID logo c  and  Yasushi Obora ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials, and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan
E-mail: obora@kansai-u.ac.jp
Fax: +81-6-6339-4026
Tel: +81-6-6368-087

b Institute for Catalysis, Hokkaido University, N-21, W-10, Sapporo 001-0021, Japan

c Comprehensive Analysis Center, SANKEN, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0057, Japan

Abstract

N,N-Dimethylformamide-stabilized Ru nanoparticles (NPs) provide a highly efficient catalyst for the Guerbet reaction of primary alcohols. DMF-modified Ru NPs were synthesized, and characterized by transition electron microscopy, and X-ray absorption spectroscopy, X-ray photoelectronspectroscopy, and Fourier-transform infrared spectroscopy. The Ru NP catalyst was highly durable during catalytic reactions under external additive/solvent-free conditions.

Graphical abstract: N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

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Article information

DOI
https://doi.org/10.1039/D2RA02381D
Article type
Paper
Submitted
13 apr 2022
Accepted
26 maj 2022
First published
06 jun 2022
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2022,12, 16599-16603

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N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

T. Nagata, K. Okada, R. Kondo, T. Toyao, K. Shimizu, T. Suzuki and Y. Obora, RSC Adv., 2022, 12, 16599 DOI: 10.1039/D2RA02381D

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