Issue 98, 2021

Transborylation of alkenylboranes with diboranes

Abstract

Exchange of boryl moieties between alkenylboranes and diboron reagents has been postulated as a stereospecific cross-metathesis pathway with concomitant formation of mixed diboron reagents. DFT calculations propose a mechanism for the stereocontrolled C(sp2)–B/B′–B′ cross-metathesis with both symmetric and non-symmetric diboron reagents.

Graphical abstract: Transborylation of alkenylboranes with diboranes

Supplementary files

Article information

Article type
Communication
Submitted
15 okt 2021
Accepted
15 nov 2021
First published
15 nov 2021

Chem. Commun., 2021,57, 13361-13364

Transborylation of alkenylboranes with diboranes

P. Dominguez-Molano, G. Bru, O. Salvado, R. J. Maza, J. J. Carbó and E. Fernández, Chem. Commun., 2021, 57, 13361 DOI: 10.1039/D1CC05815K

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