Issue 68, 2020

Slow relaxation of the magnetization, reversible solvent exchange and luminescence in 2D anilato-based frameworks

Abstract

A series of multifunctional 2D frameworks prepared with Dy(III) and the bromanilato ligand, formulated as: [Dy2(C6O4Br2)3(G)nnG with G = H2O, dimethylformamide (dmf) and dimethylsulfoxide (dmso), can exchange the coordinated and non-coordinated solvent molecules (G) in a reversible way. These multifunctional frameworks show field induced slow relaxation of the magnetization and luminescence that can be easily and reversibly modified by solvent exchange.

Graphical abstract: Slow relaxation of the magnetization, reversible solvent exchange and luminescence in 2D anilato-based frameworks

Supplementary files

Article information

Article type
Communication
Submitted
05 jun 2020
Accepted
18 jul 2020
First published
20 jul 2020

Chem. Commun., 2020,56, 9862-9865

Slow relaxation of the magnetization, reversible solvent exchange and luminescence in 2D anilato-based frameworks

S. Benmansour, A. Hernández-Paredes, A. Mondal, G. López Martínez, J. Canet-Ferrer, S. Konar and C. J. Gómez-García, Chem. Commun., 2020, 56, 9862 DOI: 10.1039/D0CC03964K

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