Issue 23, 2012
From the journal:

Chemical Communications

A novel C-5′ substituted cinchona alkaloid-derived catalyst promotes additions of alkyl thiols to nitroolefins with excellent enantioselectivity†‡

Carole Palacioa  and  Stephen J. Connon*a  

* Corresponding authors

a School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity Biomedical Sciences Institute, University of Dublin, Trinity College, Dublin 2, Ireland
E-mail: connons@tcd.ie
Fax: +35316712826

Abstract

A new bifunctional C-5′ substituted cinchona alkaloid-based catalyst promotes the first highly enantioselective additions of alkyl thiols to nitrostyrenes.

Graphical abstract: A novel C-5′ substituted cinchona alkaloid-derived catalyst promotes additions of alkyl thiols to nitroolefins with excellent enantioselectivity

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC17965B
Article type
Communication
Submitted
20 Dec 2011
Accepted
26 Jan 2012
First published
10 Feb 2012

Chem. Commun., 2012,48, 2849-2851

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A novel C-5′ substituted cinchona alkaloid-derived catalyst promotes additions of alkyl thiols to nitroolefins with excellent enantioselectivity

C. Palacio and S. J. Connon, Chem. Commun., 2012, 48, 2849 DOI: 10.1039/C2CC17965B

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