A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation

Ana J. Nuñez; Lindsey N. Shear; Naween Dahal; Ilich A. Ibarra; JiWoong Yoon; Young Kyu Hwang; Jong-San Chang; Simon M. Humphrey

doi:10.1039/C1CC14682C

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A coordination polymer of (Ph₃P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation†

Ana J. Nuñez,^a Lindsey N. Shear,^a Naween Dahal,^a Ilich A. Ibarra,^a JiWoong Yoon,^b Young Kyu Hwang,^b Jong-San Chang^b and Simon M. Humphrey*^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX, USA

^b Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology, PO Box 107, Yusung, Daejeon, Korea

Abstract

PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(III) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(I) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature.

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Article information

DOI: https://doi.org/10.1039/C1CC14682C
Article type: Communication
Submitted: 29 Jul 2011
Accepted: 27 Aug 2011
First published: 07 Oct 2011

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Chem. Commun., 2011,47, 11855-11857

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A coordination polymer of (Ph₃P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation

A. J. Nuñez, L. N. Shear, N. Dahal, I. A. Ibarra, J. Yoon, Y. K. Hwang, J. Chang and S. M. Humphrey, Chem. Commun., 2011, 47, 11855 DOI: 10.1039/C1CC14682C

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