Issue 15, 2011
From the journal:

Chemical Communications

A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework†‡

Simon S. Iremonger,a   Junmei Liang,a   Ramanathan Vaidhyanathana  and  George K. H. Shimizu*a  

* Corresponding authors

a Department of Chemistry, University of Calgary, Canada
E-mail: gshimizu@ucalgary.ca
Fax: 001 403-289-9488
Tel: 001 403-220-5347

Abstract

A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.

Graphical abstract: A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework

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Article information

DOI
https://doi.org/10.1039/C0CC04779A
Article type
Communication
Submitted
04 nov 2010
Accepted
04 feb 2011
First published
09 mar 2011

Chem. Commun., 2011,47, 4430-4432

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A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework

S. S. Iremonger, J. Liang, R. Vaidhyanathan and G. K. H. Shimizu, Chem. Commun., 2011, 47, 4430 DOI: 10.1039/C0CC04779A

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