CsAlB3O6Cl: the rational construction of a KBBF-type structure with aligned 2∞[AlB3O6Cl] layers via introducing unprecedented [AlO3Cl] tetrahedra

Haoran Liu; Jiahao Jiao; Abudukadi Tudi; Qingyu Liu; Zhihua Yang; Shilie Pan; Min Zhang

doi:10.1039/D4CC01827C

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CsAlB₃O₆Cl: the rational construction of a KBBF-type structure with aligned ²_∞[AlB₃O₆Cl] layers via introducing unprecedented [AlO₃Cl] tetrahedra†

Haoran Liu,‡^ab Jiahao Jiao,

‡^ab Abudukadi Tudi,

^ab Qingyu Liu,^ab Zhihua Yang,

^ab Shilie Pan

*^ab and Min Zhang

*^ab

Author affiliations

* Corresponding authors

^a Research Center for Crystal Materials, State Key Laboratory of Functional Materials and Devices for Special Environmental Conditions, Xinjiang Key Laboratory of Functional Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The first chloroaluminoborate, CsAlB₃O₆Cl, with innovative AlO₃Cl tetrahedra and a perfect planar arrangement of [B₃O₆] groups, was structurally designed and synthesized via chlorination of [AlO₄] tetrahedra. Simultaneously, the smooth introduction of the [AlO₃Cl] group into borates initiates the development of a chloroaluminoborate and greatly enriches the structural chemistry of aluminoborates.

This article is part of the themed collection: ChemComm 60th Anniversary Collection

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Article information

DOI: https://doi.org/10.1039/D4CC01827C
Article type: Communication
Submitted: 18 apr 2024
Accepted: 20 maj 2024
First published: 23 maj 2024

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Chem. Commun., 2024,60, 6516-6519

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CsAlB₃O₆Cl: the rational construction of a KBBF-type structure with aligned ²_∞[AlB₃O₆Cl] layers via introducing unprecedented [AlO₃Cl] tetrahedra

H. Liu, J. Jiao, A. Tudi, Q. Liu, Z. Yang, S. Pan and M. Zhang, Chem. Commun., 2024, 60, 6516 DOI: 10.1039/D4CC01827C

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