Issue 22, 2011
From the journal:

Chemical Communications

Supramolecular photocatalysis: insights into cucurbit[8]uril catalyzed photodimerization of 6-methylcoumarin†‡

Barry C. Pemberton,a   Raushan K. Singh,a   Alexander C. Johnson,a   Steffen Jockusch,b   José P. Da Silva,c   Angel Ugrinov,a   Nicholas J. Turro,b   D. K. Srivastavaa  and  J. Sivaguru*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, North Dakota State University, Fargo, USA
E-mail: sivaguru.jayaraman@ndsu.edu
Fax: (+)1-701-231-8831
Tel: (+)1-701-231-8923

b Dept. of Chemistry, Columbia University, 3000 Broadway, New York, USA
Tel: (+)1-212-854-2175

c FCT - Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal

Abstract

Guest induced shape change of the cucurbit[8]uril cavity is likely rate limiting in the supramolecular photocatalytic cycle for CB8 mediated photodimerization of 6-methylcoumarin.

Graphical abstract: Supramolecular photocatalysis: insights into cucurbit[8]uril catalyzed photodimerization of 6-methylcoumarin

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Article information

DOI
https://doi.org/10.1039/C1CC11164G
Article type
Communication
Submitted
26 feb 2011
Accepted
11 apr 2011
First published
04 maj 2011

Chem. Commun., 2011,47, 6323-6325

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Supramolecular photocatalysis: insights into cucurbit[8]uril catalyzed photodimerization of 6-methylcoumarin

B. C. Pemberton, R. K. Singh, A. C. Johnson, S. Jockusch, J. P. Da Silva, A. Ugrinov, N. J. Turro, D. K. Srivastava and J. Sivaguru, Chem. Commun., 2011, 47, 6323 DOI: 10.1039/C1CC11164G

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