A simple and sustainable strategy is proposed to construct a nanoreactor by connecting micelles with in-situ prepared ultrasmall Pd NPs to efficiently catalyze the Mizoroki-Heck reaction.
Cyrene is employed as the reaction medium in the Mizoroki–Heck cross-coupling between aryl iodides with acrylates, acrylamides or styrene. Its application in the synthesis of piperlotine A is demonstrated.
This work presents a nanomagnetic palladium complex as a sustainable catalyst for the green synthesis of butyl cinnamates via the Mizoroki–Heck reaction, demonstrating excellent catalytic performance, stability, and minimal environmental impact.
Adapting biological systems for nanoparticle synthesis opens an orthogonal Green direction in nanoscience by reducing the reliance on harsh chemicals and energy-intensive procedures.
This article reviews computational tools for the prediction of the regio- and site-selectivity of organic reactions. It spans from quantum chemical procedures to deep learning models and showcases the application of the presented tools.