Sulfondiimines are aza-analogues of sulfones and sulfoximines. Understanding their syntheses and derivatisations shall lead to more applications in medicinal and crop protecting chemistry.
We report the mild functionalization of polystyrene with primary amines and other nitrogen groups through sp3 C–H imination.
A chemodivergent protocol for the (de)hydrogenative coupling of azoarenes with benzyl alcohol is described via the N
N bond activation using an inexpensive and well-defined nickel catalyst.
Photopolymerised 4D printable PCL networks using imine based dynamic covalent chemistry exhibiting glass transition-based shape memory with over 90% shape fixity and recovery, active cell adhesion, and scavenging reactive oxygen species.
Significant advancements have recently been made in the chemistry of sulfinamidines and sulfinimidate esters. This review aims to provide an overview of the synthetic methods for the preparation and transformation of these overlooked compounds.