Here, we report the nitric oxide oxygenation (NOO) reactions of two distinct metal nitrosyls {Co–nitrosyl (S = 0) vs. Cr–nitrosyl (S = 1/2)}.
2D MNb2O6 (M = Mn, Fe, Co)/C nanohybrids with enhanced structural homogeneity were fabricated using a molten-salt route; through a favorable interfacial interaction, the reversible (de)intercalated FeNO/C nanosheets exhibit superior performances.
Electron attachment to Co(CO)3NO clusters in argon, dissociative attachment via CO and/or NO ligand losses, neutral dissociations and N
O ligand dissociation.
Our study demonstrates that encapsulating tandem nitroreductase NfsB within encapsulins, along with pore mutations, enhances enzyme activity, with cryo-EM revealing its structural architecture and multiple pore states.
Acid-catalyzed conversion of nitrite to nitric oxide at the copper(II) center: a new catalytic pathway.