Naphthyridine–2NO, a new C2-symmetric rigid tetradentate bimetallic ligand and its application in asymmetric Friedel–Crafts alkylation

Pan Hu, Ke-Lan Xu, Xi-Rui Wang, Zi-Yue Chen, Wen-Hui Zhang, Ying Zhou, Wen-Jing Zhang and Xiong-Li Liu

Org. Chem. Front., 2024, 11, 2600
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Asymmetric α-selective allylation of the amide unit of maleimides and alkenyloxindoles by dual-functional InIII/N,N′-dioxide complex

Wang-Yuren Li, Longqing Yang, Xiaoxue Tang, Wenjun Yan, Zhao Wu, Fei Wang, Shunxi Dong and Xiaoming Feng

Org. Chem. Front., 2025, 12, 2946
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Asymmetric catalytic concise synthesis of 3-(3-indolomethyl)-oxindoles for the construction of trigolute analogs

Zun Yang, Zheng Jiang, Zheng Tan, Han Yu, Xiaoming Feng and Xiaohua Liu

Chem. Commun., 2024, 60, 10926
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Asymmetric dearomatization of benzyl 1-naphthyl ethers via [1,3] O-to-C rearrangement

Hongkun Zeng, Gang Wen, Lili Lin and Xiaoming Feng

Chem. Commun., 2024, 60, 7507
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Synthesis of chiral spiro-heterocyclic azides via asymmetric [4 + 2]-cycloaddition of conjugated vinyl azides

Yican Lu, Yinhe Qu, Bingqian Yang, Hailong Zhang, Weidi Cao and Xiaoming Feng

Org. Chem. Front., 2026, 13, 64
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Phen-2NO, a new C2-symmetric rigid-featured tetradentate ligand, and its application in the asymmetric alkylation reaction of indoles

Zi-Yue Chen, Ke-Lan Xu, Xi-Rui Wang, Pan Hu, Wei-Yan Jiang, Yi-Feng Dai, Li-Jun Peng and Xiong-Li Liu

New J. Chem., 2024, 48, 6670
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Advances in organocatalytic asymmetric [3 + 3] cycloadditions: synthesis of chiral six-membered (hetero)cyclic compounds

Zi-Qi Zhu, Tian-Zhen Li, Si-Jia Liu and Feng Shi

Org. Chem. Front., 2024, 11, 5573
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Catalytic asymmetric construction of 1,5-remote Si- and C-stereocenters via desymmetrizing ene reaction of bis(methallyl)silanes

Qiuhui Cao, Yuntian Yang, Yiwen Mei, Minghui Ji, Fei Wang, Xiaoming Feng and Weidi Cao

Chem. Sci., 2025, 16, 8454
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Design of rigid chiral bipyridine-2NO tetradentate ligands: application in asymmetric catalysis

Yu-Heng Wang, Pan Hu, Xi-Rui Wang, Ke-Lan Xu, Qi-Lin Wang, Hui-Juan Wang and Xiong-Li Liu

Org. Chem. Front., 2024, 11, 1314
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Noncovalent immobilization of chiral Lewis acids on single-walled carbon nanotubes as a tool for synthetic organic aquachemistry

Taku Kitanosono, Satoshi Tanaka, Dongxin Zhang, Tomoya Hisada, Yasuhiro Yamashita and Shu Kobayashi

Chem. Sci., 2025, 16, 18686
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Chiral cobalt(ii) complex-promoted asymmetric para-Claisen rearrangement of allyl α-naphthol ethers

Hongkun Zeng, Lifeng Wang, Zhishan Su, Meijia Ying, Lili Lin and Xiaoming Feng

Chem. Sci., 2023, 14, 13979
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Asymmetric catalytic Friedel–Crafts alkylation with arenes and heteroarenes: construction of 3,3-disubstituted oxindoles

Tinghui Zhang, Ziwei Zhong, Zi Zeng, Zitong Zhu, Fei Wang, Yuxin Zhang, Xiaohua Liu, Maoping Pu and Xiaoming Feng

Org. Chem. Front., 2023, 10, 5274
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Water-enabling strategies for asymmetric catalysis

Gang Wen, Xiaoming Feng and Lili Lin

Org. Biomol. Chem., 2024, 22, 2510
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Enantioselective synthesis of C–C and C–N axially chiral pyrazole-based heterobiaryls

Jun He, Zun Yang, Lili Lin and Xiaoming Feng

Chem. Sci., 2025, 16, 20021
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Enantioselective sulfonylation to construct 3-sulfonylated oxindoles

Hongye Li, Yuqiao Zhou, Zheng Tan, Xiangyu Wang, Yuxin Zhang, Fei Wang, Xiaoming Feng and Xiaohua Liu

Chem. Commun., 2024, 60, 4354
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Brønsted acid catalyzed [4 + 2] cycloaddition for the synthesis of bisbenzannulated spiroketals with antifungal activities

Teng Hu, Yuxuan Zhao, Xiaoyan Luo, Zhong Li and Wu-Lin Yang

Org. Biomol. Chem., 2024, 22, 4656
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Tandem catalytic allylic C–H amination and asymmetric [2,3]-rearrangement via bimetallic relay catalysis

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Chem. Sci., 2024, 15, 13299
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Chiral Lewis Acid-Catalyzed Asymmetric Multicomponent Michael Reaction through [1,2]-Phospha-Brook Rearrangement

Qianchi Lin, Siyuan Wang, Rui Weng, Weidi Cao and Xiaoming Feng

Org. Lett., 2023, 25, 6262
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Enantioselective Radical Sulfonylation of 2-Naphthols and β-Ketoamides with Sodium Sulfinates

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J. Am. Chem. Soc., 2025, 147, 47339
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Merging Photocatalysis with Chiral Lewis Acid Catalysis for Enantioselective Hydrosilylation/Hydrogermylation of Electron‐Deficient Alkenes

Xiaofan Chen, Yuqiao Zhou, Ming Yang, Yuntian Yang, Xiaoming Feng and Weidi Cao

Angew Chem Int Ed, 2025, 64
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Iron-Catalyzed Asymmetric Imidation of Sulfides via Sterically Biased Nitrene Transfer

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J. Am. Chem. Soc., 2024, 146, 18050
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Iron-Catalyzed Three-Component Asymmetric Carboazidation of Alkenes with Alkanes and Trimethylsilyl Azide

Liang Ge, Yangbin Liu and Xiaoming Feng

Synlett, 2025, 36, 1962
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Catalytic Asymmetric Dearomative [2 + 2] Photocycloaddition/Ring-Expansion Sequence of Indoles with Diversified Alkenes

Liuzhen Hou, Longqing Yang, Gaofei Yang, Zhe Luo, Wanlong Xiao, Linhan Yang, Fei Wang, Liu-Zhu Gong, Xiaohua Liu, Weidi Cao and Xiaoming Feng

J. Am. Chem. Soc., 2024, 146, 23457
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Data‐Driven Modeling of N,N′‐Dioxide/Metal‐Catalyzed Asymmetric Michael Additions

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Angewandte Chemie, 2026, 138
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Construction of Chiral Spiro-Bridged Rings with Four Consecutive Stereocenters via Dearomative Diels–Alder Reactions of Anthracenes

Gaofei Yang, Longqing Yang, Zhenzhong Liu, Yilun Song, Yinhe Qu, Shunxi Dong and Xiaoming Feng

Org. Lett., 2025, 27, 5112
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Stereodivergent Construction of 3,3′-Disubstituted Oxindoles via One-Pot Sequential Allylation/Alkylation and Its Application to the Total Synthesis of Trigolute B and D

Bin Qing, Zhuang Yang, Zhenwei Wu, Zichun Zhang, Yuqiao Zhou, Xinlong Yan, Yangbin Liu and Xiaoming Feng

J. Am. Chem. Soc., 2025, 147, 7729
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Regiodivergent and Enantioselective Allylic C−H Alkylation of Allyl Ethers: Optimization, Scope, Mechanism and Application

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Angew Chem Int Ed, 2025, 64
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Asymmetric Photoenolization/Diels–Alder Reaction of 2-Methylbenzaldehydes and 2-Alkylbenzophenones with Chromones

Yuhao Mo, Lichao Ning, Zhe Luo, Liangkun Yang, Shi Tang, Shunxi Dong, Qi-Lin Zhou and Xiaoming Feng

ACS Catal., 2024, 14, 6687
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Photoinitiated Enantioselective Cycloisomerization/Addition Cascades of 2-Acyl Benzaldehydes with α,β-Unsaturated Carbonyl Compounds

Jin Wu, Liangkun Yang, Xi Lu, Fang Li, Yuhao Mo, Weidi Cao, Xiaohua Liu and Xiaoming Feng

J. Am. Chem. Soc., 2026, 148, 11249
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Asymmetric (3+2) Cycloaddition Employing β‐Fluoroalkylated α,β‐Unsaturated 2‐Acyl Imidazole Catalyzed by a Chiral‐at‐Metal Rhodium Complex

Yujie Zhao, Xiang Ji, Xue Tian, Zhifei Zhao, Jixin Pian and Shi‐Wu Li

Adv Synth Catal, 2024, 366, 1590
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Design and Synthesis of Rigid‐Featured Tertiary Amine‐Derived C2‐Symmetric Chiral Furan‐N,N′‐dioxide Ligands

Zi‐Yue Chen, Pan Hu, Xi‐Rui Wang, Ke‐Lan Xu, Yu‐Heng Wang, You‐Ping Tian, Ying Zhou and Xiong‐Li Liu

Eur J Org Chem, 2023, 26
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Photoredox-catalyzed C( sp 3 )─H radical functionalization to enable asymmetric synthesis of α-chiral alkyl phosphine

Zhenda Tan, Yangbin Liu and Xiaoming Feng

Sci. Adv., 2024, 10
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Asymmetric N-oxidation catalyzed by bisguanidinium dinuclear oxodiperoxomolybdosulfate

Wentao Wu, Esther Cai Xia Ang, Xinru Xu, Qi Wang, Hong Wang, Richmond Lee, Choon-Hong Tan and Xinyi Ye

Nat Commun, 2024, 15
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Reductant‐Free Enantioselective Aza‐Reformatsky Reaction Enabled by Synergistic Visible Light Photocatalysis and Lewis Acid Catalysis

Mingyi Jiang, Zengcheng Yu, Linhan Yang, Fei Wang, Weidi Cao, Xiaohua Liu and Xiaoming Feng

Angewandte Chemie, 2025, 137
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Synergistic catalytic synthesis of chiral γ-butenolides by trapping carboxylic oxonium ylides with enones and isatins

Xinpeng Sang, Wentao Xu, Yuqiao Zhou, Min Chen, Lili Lin, Minghui Ji, Fei Wang, Shunxi Dong and Xiaoming Feng

Sci. China Chem., 2025, 68, 5007
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Modular Chiral Bithiophene‐2NO Ligands: Synthesis and Application in Asymmetric Palladium(II)‐Catalysed Friedel‐Crafts Alkylation

Xian‐Qiao Zhu, Wu‐Wu Li, Lin‐Lu Liu, Ke‐Lan Xu, Li‐Jun Peng, Min Zhang, Xiong‐Li Liu and Wen‐Jing Zhang

Adv Synth Catal, 2025, 367
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Enantioselective homologation of helical architectures from fluorenones to phenanthrenones with enhanced circular dichroism

Shiyang Li, Shi Yan, Zhenzhong Liu, Yang Zhang, Yuqiao Zhou, Xiaoming Feng, Liang-Wen Feng and Xiaohua Liu

Nat Commun, 2025, 16
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Chiral Magnesium(II)-Catalyzed Asymmetric Hydroalkylation of Imine-Containing Vinylazaarenes through Conjugate Addition

Dong Ye, Mingyi Jiang, Lichao Ning, Wang-Yuren Li, Lili Lin and Xiaoming Feng

Org. Lett., 2025, 27, 3601
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Aza-[4 + 2]-cycloaddition of benzocyclobutenones into isoquinolinone derivatives enabled by photoinduced regio-specific C–C bond cleavage

Liangkun Yang, Shiyang Li, Lichao Ning, Hansen Zhao, Liang Zhou, Weidi Cao and Xiaoming Feng

Nat Commun, 2024, 15
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Development of Eagle‐Shaped BPE/Phe‐2NO Ligands: Switch of Enantioselectivity in Friedel–Crafts Alkylation

Jun Yang, Jing Lou, Wei Li, Xian‐Qiao Zhu, Lili Zhao, Hong‐Xing Cen and Xiong‐Li Liu

Chemistry An Asian Journal, 2025, 20
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Cobalt(II)-Catalyzed Enantioselective Propargyl Claisen Rearrangement: Access to Allenyl-Substituted Quaternary β-Ketoesters

Ya-Ping Wang, Xing-Ping Zhang, Ming-Sheng Xie and Hai-Ming Guo

Org. Lett., 2023, 25, 7105
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Asymmetric Three-Component Radical Alkene Carboazidation by Direct Activation of Aliphatic C–H Bonds

Liang Ge, Hongkai Wang, Yangbin Liu and Xiaoming Feng

J. Am. Chem. Soc., 2024, 146, 13347
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Visible-Light-Promoted Enantioselective Acylation and Alkylation of Aldimines Enabled by 9-Fluorenone Electron-Shuttle Catalysis

Ziwei Zhong, Hongda Wu, Xiaofan Chen, Yao Luo, Longqing Yang, Xiaoming Feng and Xiaohua Liu

J. Am. Chem. Soc., 2024, 146, 20401
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Merging Photocatalysis with Chiral Lewis Acid Catalysis for Enantioselective Hydrosilylation/Hydrogermylation of Electron‐Deficient Alkenes

Xiaofan Chen, Yuqiao Zhou, Ming Yang, Yuntian Yang, Xiaoming Feng and Weidi Cao

Angewandte Chemie, 2025, 137
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Synthesis of γ-Butyrolactones with Chiral Quaternary–Tertiary Stereocenters via Catalytic Asymmetric Mukaiyama–Michael Addition

Qifan Xu, Lichao Ning, Wentao Xu, Lili Lin and Xiaoming Feng

Org. Lett., 2024, 26, 9665
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Asymmetric Catalytic Radical Reactions Enabled by Chiral N,N′-Dioxide–Metal Complexes

Weidi Cao, Xiaohua Liu and Xiaoming Feng

Acc. Chem. Res., 2025, 58, 2496
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Iron‐Catalyzed Asymmetric α‐Alkylation of 2‐Acylimidazoles via Dehydrogenative Radical Cross‐Coupling with Alkanes

Nian Xu, Maoping Pu, Han Yu, Gaofei Yang, Xiaohua Liu and Xiaoming Feng

Angew Chem Int Ed, 2024, 63
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Regiodivergent and Enantioselective Allylic C−H Alkylation of Allyl Ethers: Optimization, Scope, Mechanism and Application

Hongkai Wang, Lijuan Song, Jing Huang, Fule Wu, Zhuang Yang, Yangbin Liu, Yun‐Dong Wu and Xiaoming Feng

Angewandte Chemie, 2025, 137
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Visible Light‐Promoted Enantioselective Catalytic Alkylation of α‐Ketoamides with Hydrocarbons

Han Yu, Zun Yang, Hongda Wu, Yao Luo, Weidi Cao, Xiaohua Liu and Xiaoming Feng

ChemCatChem, 2025, 17
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Catalytic asymmetric constructions of nitrogen, boron and carbon continuous stereogenic centers

Guan Zhang, Junyi Jia, Xuzhao Du, Bofan Feng, Kai Yang, Peiyuan Yu and Qiuling Song

Nat Commun, 2025, 16
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Reductant‐Free Enantioselective Aza‐Reformatsky Reaction Enabled by Synergistic Visible Light Photocatalysis and Lewis Acid Catalysis

Mingyi Jiang, Zengcheng Yu, Linhan Yang, Fei Wang, Weidi Cao, Xiaohua Liu and Xiaoming Feng

Angew Chem Int Ed, 2025, 64
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Regioselective and asymmetric allylic alkylation of vinyl epoxides for the construction of allylic alcohols via synergistic catalysis

Min Chen, Longqing Yang, Yuzhen Li, Yinhe Qu, Guihua Pan, Xiaoming Feng and Xiaohua Liu

Sci. China Chem., 2024, 67, 542
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Catalytic Asymmetric Synthesis of Axially and Centrally Chiral 1,2-Dihydrobenzofuro[3,2-b]pyridines through a [2 + 2] Cycloaddition/Retroelectrocyclization/Re-Cycloaddition Cascade

Wanlong Xiao, Fang Li, Xiaohua Liu, Weidi Cao and Xiaoming Feng

Org. Lett., 2023, 25, 8005
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Iron‐Catalyzed Asymmetric α‐Alkylation of 2‐Acylimidazoles via Dehydrogenative Radical Cross‐Coupling with Alkanes

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Angewandte Chemie, 2024, 136
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Asymmetric Synthesis of 3-Alkyl 3-Alkyloxy-2-oxindoles by Enantioconvergent Alkoxylation with Alcohols

Yilun Song, Deyang Liu, Shunxi Dong and Xiaoming Feng

Synthesis, 2025, 57, 2241
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Asymmetric Dearomative [2 + 2] Photocycloaddition of Quinoline and Indole Derivatives with Bicyclo[1.1.0]butanes

Jia Yang, Longqing Yang, Yuexing Zhao, Liuzhen Hou, Yong Qiu, Guihua Pan, Xiaohua Liu, Xiaoming Feng and Shunxi Dong

J. Am. Chem. Soc., 2025, 147, 35755
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Catalytic Enantioselective Methods for Synthesis of 1,2-Amino Tertiary Alcohols and Their Analogues

Steven J. Malcolmson and Faraan Rahim

Chem. Rev., 2025, 125, 10765
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Visible-Light-Induced Enantioselective Dearomative [2+2]-Cycloaddition/Ring-Expansion Sequence of Indoles with Simple Alkenes

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Synlett, 2025, 36, 944
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Photoinduced Asymmetric [4 + 2] Cycloaddition of Benzocyclobutenones with Ketones into 3,4-Dihydroisocoumarins

Hansen Zhao, Xi Lu, Liangkun Yang, Sile Li, Xiaoming Feng and Weidi Cao

Org. Lett., 2025, 27, 8656
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A Remarkable Influence of La(III)/N,N′-Dioxide Structure on Asymmetric Formal Substitution of 3-Bromo-3-substituted Oxindoles with TMSCN

Zi Zeng, Longqing Yang, Zhijie Xiao, Long Chen, Ziwei Zhong, Fei Wang, Xiaohua Liu, Shunxi Dong and Xiaoming Feng

ACS Catal., 2024, 14, 2908
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Pathway to P(V)-Stereogenic Phosphoramidates by Enantioselective Yttrium Catalysis

Brian S. Daniels, Bryan G. Blackburn, Silas J. Scribner and Vy M. Dong

J. Am. Chem. Soc., 2025, 147, 21339
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Asymmetric Synthesis of Hydrodibenzofurans from Norcaradienes: Kinetic Resolution via [3 + 2] Cycloaddition with Quinones

Siyuan Wang, Lichao Ning, Zhiqiang Li, Xiaoming Feng and Xiaohua Liu

Org. Lett., 2024, 26, 3844
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Solvent-Controlled Enantioselective Allylic C–H Alkylation of 2,5-Dihydrofuran via Synergistic Palladium/Nickel Catalysis

Fule Wu, Hongkai Wang, Zhenwei Wu, Yangbin Liu and Xiaoming Feng

J. Am. Chem. Soc., 2025, 147, 16237
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Chiral N,N′-Dioxide Ligands Tune Diastereoselectivity in Mg(II)-Catalyzed Asymmetric Ring-Opening Desymmetrization of Azetidiniums

Zhaojing Li, Yan Wang, Deyang Liu, Lichao Ning, Maoping Pu, Lili Lin and Xiaoming Feng

Org. Lett., 2023, 25, 7612
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Catalytic asymmetric inverse-electron-demand Diels–Alder reaction of 2-pyrones with aryl enol ethers

Fangqing Zhang, Yu Wang, Zhenda Tan, Yangbin Liu, Lijuan Song and Xiaoming Feng

Chinese Chemical Letters, 2025, 36, 110581
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Copper-catalyzed asymmetric dearomatizing amination of 2-naphthols: Csp2–N coupling via 1,3-reductive elimination

Aying Yihuo, Maoping Pu, Zheng Tan, Jibang Liao, Jiuqi Tan, Qi-Lin Zhou, Xiaohua Liu and Xiaoming Feng

Sci. China Chem., 2024, 67, 2694
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Construction of Multi‐Substituted Strained Carbocycles Enabledby Enantioselective Reduction with Sodium Borohydride

Shaowei Wang and Ping Lu

Chin. J. Chem., 2025, 43, 3610
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Photoinduced Asymmetric Dearomative Hydroalkylation of Electron-Deficient Indoles with Alkyltrifluoroborates

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Org. Lett., 2025, 27, 9782
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Data‐Driven Modeling of N,N′‐Dioxide/Metal‐Catalyzed Asymmetric Michael Additions

Miao‐Jiong Tang, Tinghui Zhang, Qiuhao Huang, Shuwen Li, Rui Liu, Hongye Li, Xiaofan Chen, Shunxi Dong, Xiaohua Liu, Xiaoming Feng and Xin Hong

Angew Chem Int Ed, 2026, 65
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