Issue 69, 2022

Isolation of uranium(iii) primary phosphido complexes

Abstract

Low-valent uranium(III) primary phosphido complexes supported by hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) were synthesized with phosphines of varying steric and electronic profiles. Compounds were characterized by multinuclear NMR spectroscopy (1H, 11B, 31P NMR), infrared spectroscopy, electronic absorption spectroscopy, X-ray crystallography, and quantum chemical calculations.

Graphical abstract: Isolation of uranium(iii) primary phosphido complexes

Supplementary files

Article information

Article type
Communication
Submitted
18 apr 2022
Accepted
25 júl 2022
First published
11 aug 2022

Chem. Commun., 2022,58, 9630-9633

Author version available

Isolation of uranium(III) primary phosphido complexes

D. Perales, R. Bhowmick, M. Zeller, P. Miro, B. Vlaisavljevich and S. C. Bart, Chem. Commun., 2022, 58, 9630 DOI: 10.1039/D2CC02207A

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