KB3H8: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols

Xinying Li; Tongge Mi; Wenjing Guo; Zhongrui Ruan; Yu Guo; Yan-Na Ma; Xuenian Chen

doi:10.1039/D1CC05638G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

KB₃H₈: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols†

Xinying Li,^a Tongge Mi,^b Wenjing Guo,^a Zhongrui Ruan,^a Yu Guo,^b Yan-Na Ma*^a and Xuenian Chen

*^a

Author affiliations

* Corresponding authors

^a Green catalysis center and College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450000, China
E-mail: Xuenian_Chen@zzu.edu.cn, mayanna@zzu.edu.cn

^b Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China

Abstract

Selective reduction of aldehydes and ketones to their corresponding alcohols with KB₃H₈, an air- and moisture-stable, nontoxic, and easy-to-handle reagent, in water and THF has been explored under an air atmosphere for the first time. Control experiments illustrated the good selectivity of KB₃H₈ over NaBH₄ for the reduction of 4-acetylbenzaldehyde and aromatic keto esters.

This article is part of the themed collections: Boron Chemistry in the 21st Century: From Synthetic Curiosities to Functional Molecules and Chemical Communications HOT articles

Download options Please wait...

Supplementary files

Supplementary information PDF (2998K)

Article information

DOI: https://doi.org/10.1039/D1CC05638G
Article type: Communication
Submitted: 07 okt 2021
Accepted: 03 nov 2021
First published: 04 nov 2021

Download Citation

Chem. Commun., 2021,57, 12776-12779

Permissions

Request permissions

KB₃H₈: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols

X. Li, T. Mi, W. Guo, Z. Ruan, Y. Guo, Y. Ma and X. Chen, Chem. Commun., 2021, 57, 12776 DOI: 10.1039/D1CC05638G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications