Polyoxometalate adsorbed in a metal–organic framework for electrocatalytic dopamine oxidation†
Abstract
A redox-active vanadium-based polyoxometalate, V10O28, was post-synthetically immobilized into a water-stable zirconium-based metal–organic framework, NU-902. The adsorbed V10O28 in NU-902 renders charge hopping in the framework in aqueous electrolytes, and the obtained V10O28@NU-902 can be used as a heterogeneous electrocatalyst for electrochemical dopamine sensors.
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