Issue 95, 2019
From the journal:

Chemical Communications

Outer surface interactions to drive cucurbit[8]uril-based supramolecular frameworks: possible application in gold recovery†

Li-Xia Chen,a   Ming Liu,a   Yun-Qian Zhang, ORCID logo a   Qian-Jiang Zhu,a   Jing-Xin Liu,*b   Bi-Xue Zhu*a  and  Zhu Tao ORCID logo *a  

* Corresponding authors

a Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China
E-mail: gzutao@263.net

b College of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, China

Abstract

Q[8]-based honeycomb-like frameworks can be obtained in [AuCl4]−-free aqueous HNO3 solution and aqueous HCl and HNO3 solutions that contain [AuCl4]−. The outer surface interaction of Q[8] with planar inorganic anions [AuCl4]− and NO3− is the main driving force. These frameworks exhibit a high selectivity for imprisoning [AuCl4]− that could establish a process for gold recovery.

Graphical abstract: Outer surface interactions to drive cucurbit[8]uril-based supramolecular frameworks: possible application in gold recovery

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Article information

DOI
https://doi.org/10.1039/C9CC07147D
Article type
Communication
Submitted
12 sep 2019
Accepted
04 nov 2019
First published
08 nov 2019

Chem. Commun., 2019,55, 14271-14274

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Outer surface interactions to drive cucurbit[8]uril-based supramolecular frameworks: possible application in gold recovery

L. Chen, M. Liu, Y. Zhang, Q. Zhu, J. Liu, B. Zhu and Z. Tao, Chem. Commun., 2019, 55, 14271 DOI: 10.1039/C9CC07147D

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