Two-electron oxidation of a homoleptic U(iii) guanidinate complex by diphenyldiazomethane†
Abstract
Reaction of the first homoleptic U(III) guanidinate complex with diphenyldiazomethane results in two-electron oxidation of U(III) to U(V) and isolation of a U(V) hydrazido complex. Corresponding U(V) imido, U(V) oxo, and U(IV) azido complexes were also synthesized for structural comparison.
- This article is part of the themed collection: New molecules and materials from the f-block